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Effect of compatibilization in injection-molded polycarbonate and liquid crystalline polymer blend

机译:相容性对注塑聚碳酸酯和液晶聚合物共混物的影响

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摘要

The effect of compatibilizing polycarbonate (PC) and LC5000, a thermotropic liquid crystalline polymer consisting of 80/20% of hydroxybenzoic acid and poly(terephthalate) with a laboratory synthesized compatibilizer was studied. The compatibilizer was synthesized by transesterification of PC and LC5000 with the aid of a catalyst. The effect of compatibilization was investigated by studying the mechanical and morphological properties of injection-molded plaques with different thicknesses. Substantial improvement was observed in the mechanical properties after compatibilization. Significant enhancement in the fibrillation was also observed in the samples after addition of compatibilizer. The surface finish of the compatibilized samples was smooth and homogenous as compared to the uncompatibilized samples. The skin-core phenomenon in the tensile fractured surfaces was less obvious in the former samples, indicating better adhesion and homogeneity. These morphological studies showed that the mechanical properties enhancement lay in improved fibrillation and interfacial adhesion between the dispersed and major phases. (C) 2002 John Wiley Sons, Inc. [References: 23]
机译:研究了由实验室合成的增容剂对聚碳酸酯(PC)和LC5000(由80/20%的羟基苯甲酸和聚对苯二甲酸酯组成的热致液晶聚合物)的增容效果。通过在催化剂的作用下PC和LC5000的酯交换反应合成增容剂。通过研究不同厚度的注塑板的力学和形态学特性,研究了相容化的效果。相容后,观察到机械性能有了很大的改善。加入增容剂后,样品中的原纤化也明显增强。与不相容样品相比,相容样品的表面光洁度是均匀的。在以前的样品中,拉伸断裂表面的皮芯现象不那么明显,表明具有更好的附着力和均匀性。这些形态学研究表明,机械性能的提高在于分散相和主相之间的原纤化和界面粘合性的改善。 (C)2002 John Wiley Sons,Inc. [参考:23]

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