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CONDUCTIVE COATING FILMS BASED ON LOW DENSITY IN2O3 POWDERS AND POLYMER LATEXES

机译:基于低密度In2O3粉末和聚合物胶乳的导电涂层膜

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Several kinds of conductive coating films were prepared from a low-density indium(III) oxide powder (which was employed because it provides a much higher volume for the same weight) and polymer latexes. The low-density In2O3, which is an electrically conductive pigment, was prepared by pyrolysis followed by the combustion of water-swellable polymer microspheres imbibed with In(NO3)(3), the precursor of In2O3. Either acrylamide/N,N'-methylenebisacrylamide or poly(vinylalcohol)/glutaricdialdehyde was used to generate spherical hydrogel particles. The polymer latexes with which the In2O3 was mixed had a soft core and a hard shell structure to ensure that the coating film has suitable mechanical properties in addition to conductivity. Acrylonitrile/butadiene/styrene copolymer ABS or acrylonitrile/butylacrylate/styrene copolymer ABAS latexes were used as binders for the conductive pigment. The powder coating followed by hot pressing, the water-borne coating consisting of low-density In2O3 and polymer latexes followed by curing, or the colloidal dispersion coating was used to deposit flexible conductive coating films on polyester sheets. The conductive pigment density and the polymer latexes' size and flowability are the factors that affect the characteristics of the film. We found that the colloidal suspension coating procedure based on ABAS latexes achieves better electrical and mechanical properties for the coating films. (C) 1996 John Wiley & Sons, Inc. [References: 4]
机译:由低密度的氧化铟(III)粉末(由于在相同的重量下其体积要大得多)和聚合物胶乳制备了几种导电涂膜。通过热解,然后燃烧吸收了In2O3前体In(NO3)(3)的水溶胀性聚合物微球,可以制备低密度In2O3,它是一种导电颜料。丙烯酰胺/ N,N'-亚甲基双丙烯酰胺或聚乙烯醇/戊二醛均用于生成球形水凝胶颗粒。与In 2 O 3混合的聚合物胶乳具有软核和硬壳结构,以确保涂膜除了导电性之外还具有合适的机械性能。丙烯腈/丁二烯/苯乙烯共聚物ABS或丙烯腈/丙烯酸丁酯/苯乙烯共聚物ABAS胶乳用作导电颜料的粘合剂。粉末涂料随后热压,由低密度In2O3和聚合物胶乳组成的水性涂料,然后固化,或胶体分散涂料用于在聚酯片材上沉积柔性导电涂料薄膜。导电颜料的密度以及聚合物胶乳的尺寸和流动性是影响薄膜特性的因素。我们发现,基于ABAS胶乳的胶体悬浮液涂覆工艺可为涂膜实现更好的电气和机械性能。 (C)1996 John Wiley&Sons,Inc. [参考:4]

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