AQUEOUS POLYMERIZATION OF ACRYLAMIDE BY ELECTROLITICALLY GENERATED KMNO4 ORGANIC ACID REDOX SYSTEMS

Sarac AS.; Coka V.; Soydan AB.

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AQUEOUS POLYMERIZATION OF ACRYLAMIDE BY ELECTROLITICALLY GENERATED KMNO4 ORGANIC ACID REDOX SYSTEMS

机译：电解生成的KMNO4有机酸氧化还原体系对丙烯酰胺的水聚合

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Polymerization of acrylamide was carried out with potassium permanganate-malonic acid, potassium permanganate-tartaric acid, and potassium permanganate-citric acid redox initiator systems with and without electrolysis. The effect of potassium permanganate concentration, acrylamide concentration, and temperature on the polymerization yield was studied and molecular weights of polymers were determined and compared with electrolytic conditions. At low concentrations of potassium permanganate, continuously supplying Mn(III) has an advantage over the nonelectrolytic method for which polymerization did not occur under these conditions. (C) 1996 John Wiley & Sons, Inc. [References: 14]

机译：丙烯酰胺的聚合反应是在高锰酸钾-丙二酸，高锰酸钾-酒石酸和高锰酸钾-柠檬酸氧化还原引发剂体系中进行和不进行电解。研究了高锰酸钾浓度，丙烯酰胺浓度和温度对聚合收率的影响，确定了聚合物的分子量并将其与电解条件进行了比较。在高锰酸钾浓度低的情况下，连续供应Mn（III）优于在这种条件下不会发生聚合的非电解方法。（C）1996 John Wiley＆Sons，Inc. [参考：14]

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《Journal of Applied Polymer Science》 |1996年第1期|共6页
作者
Sarac AS.; Coka V.; Soydan AB.;
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正文语种 eng
中图分类高分子化学（高聚物）;高分子化合物产品;有机化学;
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1. AQUEOUS POLYMERIZATION OF ACRYLAMIDE BY ELECTROLITICALLY GENERATED KMNO4 ORGANIC ACID REDOX SYSTEMS [J] . Sarac AS., Coka V., Soydan AB. Journal of Applied Polymer Science . 1996,第1期

机译：电解生成的KMNO4有机酸氧化还原体系对丙烯酰胺的水聚合
2. Polymerization of acrylamide initiated by KMnO4-cyclohexanone redox system in presence of surfactant [J] . Patra M., Sinha BK. Journal of Macromolecular Science. Pure and Applied Chemistry . 2000,第7期

机译：在表面活性剂存在下，由KMnO4-环己酮氧化还原体系引发的丙烯酰胺聚合
3. Polymerization of acrylamide in aqueous medium initiated by a redox system of 4-carboxybenzophenone and sulfur-containing amino acids [J] . Andrzej Wrzyszczynski Polymer: The International Journal for the Science and Technology of Polymers . 1999,第11期

机译：4-羧基二苯甲酮和含硫氨基酸的氧化还原体系引发的丙烯酰胺在水介质中的聚合
4. Studies on graft copolymerization of Acrylamide on to Guar gum using Vanadium(v) / Mandelic Acid Redox Pair [C] . Rajesh Kumar, Mala Tripathi, Kunj Behari PMSE Symposia . 2003

机译：使用钒（V）/扁桃酸氧化还原对丙烯酰胺接枝丙烯酰胺接枝共聚的研究
5. Stimuli-responsive polyampholytes based on acrylamide and amino acid derived N-substituted acryoyl monomers: Synthesis, characterization, and aqueous solution behavior ofpH- and salt-responsive model systems. [D] . Ezell, Ryan Gillis. 2006

机译：基于丙烯酰胺和氨基酸衍生的N取代的丙烯酰基单体的刺激响应性两性电解质：pH和盐响应模型系统的合成，表征和水溶液行为。
6. A Novel Aqueous Two Phase System Composed of a Thermo-Separating Polymer and an Organic Solvent for Purification of Thermo-Acidic Amylase Enzyme from Red Pitaya (Hylocereus polyrhizus) Peel [O] . Mehrnoush Amid, Yazid Manap, Nor Khanani Zohdi 2014

机译：一种由热分离聚合物和有机溶剂组成的新型水两相系统用于从红火龙果皮中纯化热酸淀粉酶。
7. Polymerization of acrylamide initiated with Ce(IV)- and KMnO4–mercaptosuccinic acid redox systems in acid-aqueous medium [O] . 2007

机译：在酸 - 水介质中用Ce（IV） - 和KmnO4-巯基琥珀酸氧化还原体系引发的丙烯酰胺聚合

AQUEOUS POLYMERIZATION OF ACRYLAMIDE BY ELECTROLITICALLY GENERATED KMNO4 ORGANIC ACID REDOX SYSTEMS

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