首页> 外文期刊>Journal of Applied Polymer Science >STABILIZATION OF FILLED POLYSILOXANE ELASTOMERS TO CYCLIC STRESS AT ELEVATED TEMPERATURE THROUGH USE OF ZINC OXIDE FILLERS
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STABILIZATION OF FILLED POLYSILOXANE ELASTOMERS TO CYCLIC STRESS AT ELEVATED TEMPERATURE THROUGH USE OF ZINC OXIDE FILLERS

机译:通过使用氧化锌填料在高温下将填充的聚硅氧烷弹性体稳定到循环应力

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摘要

The susceptibility of filled polysiloxane elastomers to cyclic stress at elevated temperatures is investigated. It is shown that zinc oxide fillers, unlike other fillers examined previously, can produce filled elastomers with remarkable stability to combined mechanical and thermal stresses. The influences of filler concentration, diphenylsiloxane incorporation, and molecular weight between network crosslinks are examined. The data demonstrate that the elastomer stability to cyclic stress at elevated temperature increases with increasing filler content and does not correlate with diphenylsiloxane content. It is suggested that chemical interactions between the polysiloxane network and the filler surfaces control the response to cyclic stress at elevated temperature and that the response strongly depends on the type of filler selected. (C) 1997 John Wiley & Sons, Inc. [References: 29]
机译:研究了填充的聚硅氧烷弹性体在高温下对循环应力的敏感性。结果表明,氧化锌填料与先前检查的其他填料不同,可以生产出对复合机械应力和热应力具有显着稳定性的填充弹性体。研究了填料浓度,二苯基硅氧烷掺入和网络交联之间分子量的影响。数据表明,弹性体在高温下对循环应力的稳定性随填料含量的增加而增加,并且与二苯基硅氧烷的含量无关。建议在升高的温度下,聚硅氧烷网络与填料表面之间的化学相互作用控制对循环应力的响应,并且该响应强烈取决于所选填料的类型。 (C)1997 John Wiley&Sons,Inc. [参考:29]

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