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Graft copolymerization of starch-AN initiated by potassium permanganate

机译:高锰酸钾引发淀粉-AN的接枝共聚

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The initiating ability of the potassium permanganate in the graft copolymerization of acrylonitrile onto starch was studied. The results indicate that the grafting parameters, such as concentrations of potassium permanganate, acrylonitrile, starch, and catalyst acids, all have significant effects on the graft copolymerization and the components of the graft copolymers, and this offers methods to adjust the properties of the graft copolymers. The sources of starch and corn starch derivatives both affected the components of the graft copolymers, which showed the influence of functional group on the grafting ability of starch. The preheat treatment and preoxidation of starch, as well as the adding sequence of the reactants all influenced the graft copolymerization, from which some suggestions about the grafting procession could be obtained. (C) 1998 John Wiley & Sons, Inc. [References: 22]
机译:研究了高锰酸钾在丙烯腈与淀粉接枝共聚中的引发能力。结果表明,高锰酸钾,丙烯腈,淀粉和催化剂酸等接枝参数均对接枝共聚反应和接枝共聚物的组成有重要影响,这为调节接枝性能提供了方法。共聚物。淀粉和玉米淀粉衍生物的来源均影响接枝共聚物的组分,这表明官能团对淀粉接枝能力的影响。淀粉的预热处理和预氧化,以及反应物的添加顺序都影响了接枝共聚,从中可以得到有关接枝过程的一些建议。 (C)1998 John Wiley&Sons,Inc. [参考:22]

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