A Novel Polymer Electrolyte Based on Polydioxolane Polyurethane with Na~+ Single-Ionic Conductivity

Wang Lei; Yang Bing; Wang Xin-Ling; Tang Xiao-Zhen

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A Novel Polymer Electrolyte Based on Polydioxolane Polyurethane with Na~+ Single-Ionic Conductivity

机译：Na〜+单离子电导率的新型基于聚二氧戊环聚氨酯的聚合物电解质

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A series of novel polyurethane ionomers with polydioxolane (PDXL) as soft segment was prepared and characterized by Fourier teansfoem infrated spectroscopy,differential scanning calorimetry,and dynamic mechanical analysis.The ionomers obtained were Na~+ single-ionic conductors.Their ionic conductivity and water absorption were tested.At medium temperature (>75 deg C),the conductivity of approx 10~(-5) s com~(-1) was reached.The temperature dependence of conductivity could not be well expressed by both Arrhenius and VTF equations.When ionization level was fixed,the conductivity increased as the Mn of PDXL decreased.We also discussed the effect of ionization level on water absorption.

机译：制备了一系列以聚二氧戊环（PDXL）为软链段的新型聚氨酯离聚物，并通过傅里叶红外光谱，差示扫描量热法和动态力学分析对其进行了表征，得到的离聚物为Na〜+单离子导体，其离子电导率和水在中等温度（> 75摄氏度）下，电导率达到约10〜（-5）s com〜（-1）.Arrhenius和VTF方程均不能很好地表达电导率的温度依赖性当电离水平固定时，电导率随PDXL Mn的降低而增加。我们还讨论了电离水平对吸水率的影响。

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来源
《Journal of Applied Polymer Science》 |1999年第10期|共9页
作者
Wang Lei; Yang Bing; Wang Xin-Ling; Tang Xiao-Zhen;
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正文语种 eng
中图分类高分子化学（高聚物）;高分子化合物产品;有机化学;
关键词
single-ionic conductors; polyurethane ionomers; polydioxolane; ionic conductivity; water absorption;

机译：单离子导体;聚氨酯离聚物;聚二氧戊环;离子电导率;吸水率;

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专利

1. A Novel Polymer Electrolyte Based on Polydioxolane Polyurethane with Na~+ Single-Ionic Conductivity [J] . Wang Lei, Yang Bing, Wang Xin-Ling, Journal of Applied Polymer Science . 1999,第10期

机译：Na〜+单离子电导率的新型基于聚二氧戊环聚氨酯的聚合物电解质
2. Solid polymer electrolytes, 2 - Preparation and ionic conductivity of solid polymer electrolytes based on segmented polysiloxane-modified polyurethane [J] . Kuo PL., Liang WJ., Lin CL. Macromolecular chemistry and physics . 2002,第1期

机译：固体聚合物电解质，2-基于分段聚硅氧烷改性的聚氨酯的固体聚合物电解质的制备和离子电导率
3. Conductivities and spectroscopic studies of polymer electrolytes based on linear polyurethane and hybrid and copolymer of linear and hyperbranched polyurethanes [J] . Hong L., Shi LY., Tang XZ. Macromolecules . 2003,第13期

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4. The Effect of Carboxymethyl Cellulose as Bio Filler on Ionic Conductivity and Physical Property of Waste Cooking Oil Based Polyurethane Composite Polymer Electrolyte [C] . Syuhada Mohd Tahir, Norhatikah Alias International Conference on Global Sustainability and Chemical Engineering . 2019

机译：羧甲基纤维素作为生物填料对废料烹饪油基聚氨酯复合聚合物电解质离子电导率和物质的影响
5. POLYPHOSPHAZENE-BASED SOLID ELECTROLYTES: SYNTHESIS, COMPLEX FORMATION, CONDUCTIVITY, AND ION TRANSPORT (POLYMER, CONDUCTIVITY). [D] . BLONSKY, PETER MILLER. 1986

机译：基于聚磷腈的固体电解质：合成，复杂形成，电导率和离子传输（聚合物，电导率）。
6. Physico-Chemical Thermal and Electrochemical Analysis of Solid Polymer Electrolyte from Vegetable Oil-Based Polyurethane [O] . Siti Rosnah Mustapa, Min Min Aung, Marwah Rayung 2021

机译：植物油基聚氨酯固体聚合物电解质的物理化学热和电化学分析
7. An Ecofriendly Gel Polymer Electrolyte Based on Natural Lignocellulose with Ultrahigh Electrolyte Uptake and Excellent Ionic Conductivity for Alkaline Supercapacitors [O] . -1

机译：基于天然木质纤维素的Ecofriengly凝胶聚合物电解质，具有超高电解质吸收和优异的碱性超级电容器的优异离子电导率
8. Polydioxolane Polymer Electrolyte [R] . Foos, J. S., Erker, S. M. 1986

机译：聚二氧戊环聚合物电解质

A Novel Polymer Electrolyte Based on Polydioxolane Polyurethane with Na~+ Single-Ionic Conductivity

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