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Elastic property of polyvinyl alcohol gel with boric acid as a crosslinking agent

机译:以硼酸为交联剂的聚乙烯醇凝胶的弹性

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摘要

The elastomers of polyvinyl alcohol gel were made from the polyvinyl alcohol polymer, with boric acid added as a crosslinking agent, in the mixed solvent of dimethyl sulfoxide and water. From the experimental results, the viscosity of polyvinyl alcohol solution is found to increase not only with an increment of boric acid content, but also with the temperature in the range of 70°C approx. 100°C, although the viscosity is decreased in the range of 30°C approx. 70°C. Moreover, the molecular mass between junctions of polyvinyl alcohol gel is calculated from the rubber elastic theory and found to be decreased with the increment of boric acid content. We also evaluated the values of Young's modulus of polyvinyl alcohol gel, E, E*, and the elastic parameters C1 and C2 of the Mooney-Rivlin equation, according to Hook's law and theory of rubber elasticity. Based on these, the polyvinyl alcohol gel behaves as a good rubberlike elastic property.
机译:聚乙烯醇凝胶的弹性体由聚乙烯醇聚合物制成,在二甲基亚砜和水的混合溶剂中加入硼酸作为交联剂。根据实验结果,发现聚乙烯醇溶液的粘度不仅随着硼酸含量的增加而增加,而且随着温度在大约70℃左右而增加。尽管粘度在约30°C的范围内降低,但仍为100°C。 70℃。此外,聚乙烯醇凝胶的结合点之间的分子量是根据橡胶弹性理论计算的,发现随着硼酸含量的增加而降低。根据胡克定律和橡胶弹性理论,我们还评估了聚乙烯醇凝胶的杨氏模量E,E *以及门尼-里夫林方程的弹性参数C1和C2。基于这些,聚乙烯醇凝胶表现出良好的橡胶状弹性。

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