Formulation/property relationships in radiation-cured poly(urethane methacrylate) pressure-sensitive adhesives. I. Incorporation of hydrophilic polyols

Mllan E.J.; Webster I.

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Formulation/property relationships in radiation-cured poly(urethane methacrylate) pressure-sensitive adhesives. I. Incorporation of hydrophilic polyols

机译：辐射固化的聚（甲基丙烯酸氨基甲酸乙酯）压敏胶粘剂的配方/性质关系。 I.亲水多元醇的掺入

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Electron beam-curable urethane methacrylate oligomers were prepared which, when cured, produce pressure-sensitive adhesives. The effect of replacing hydrophobic blocks with more hydrophilic polyols in the prepolymer, in order to increase the moisture vapor transmission rates (MVTRs), was investigated. Subsequent effects on the resulting adhesive properties were also monitored. The MVTRs of the adhesives were found to increase upon incorporation of poly(ethylene glycol) but with a detrimental effect on the adhesive properties. The nature of the change in properties was related to the distribution of ethylene oxide units in the prepolymer.

机译：制备了电子束可固化的氨基甲酸酯甲基丙烯酸酯低聚物，其在固化时产生压敏粘合剂。研究了在预聚物中用更多的亲水性多元醇代替疏水性嵌段的效果，以提高水蒸气透过率（MVTR）。还监测了对所得粘合性能的后续影响。发现粘合剂的MVTR在加入聚（乙二醇）时增加，但是对粘合剂性能有不利影响。性质变化的性质与预聚物中环氧乙烷单元的分布有关。

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《Journal of Applied Polymer Science》 |1999年第14期|共6页
作者
Mllan E.J.; Webster I.;
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正文语种 eng
中图分类高分子化学（高聚物）;高分子化合物产品;有机化学;
关键词
Oligomers; Polyurethanes; Polyacrylates; Curing; Electron beams; Plastic adhesives; Polyethylene glycols; Moisture; Vapors; Pressure sensitive adhesives; Moisture vapor transmission rates;

机译：低聚物;聚氨酯;聚丙烯酸酯;固化;电子束;塑料胶粘剂;聚乙二醇;水分;蒸气;压敏胶粘剂;湿气透过率;

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专利

1. Formulation/property relationships in radiation-cured poly(urethane methacrylate) pressure-sensitive adhesives. I. Incorporation of hydrophilic polyols [J] . Mllan E.J., Webster I. Journal of Applied Polymer Science . 1999,第14期

机译：辐射固化的聚（甲基丙烯酸氨基甲酸乙酯）压敏胶粘剂的配方/性质关系。 I.亲水多元醇的掺入
2. Structure-property relationships of poly(urethane-urea)s with ultra-low monol content poly(propylene glycol) soft segments. Part II. Influence of low molecular weight polyol components [J] . OSickey MJ., Lawrey BD., Wilkes GL. Polymer: The International Journal for the Science and Technology of Polymers . 2002,第26期

机译：具有超低一元醇含量的聚丙二醇软链段的聚氨基甲酸酯-脲的结构-性质关系。第二部分低分子量多元醇组分的影响
3. New poly (urethane-methacrylate)s obtained by adjusting the structure of the polyols moieties: Synthesis, transparent, thermal and mechanical properties [J] . Gao L., Zhou L., Fang S., Journal of Polymer Research . 2011,第4期

机译：通过调节多元醇部分的结构获得的新型聚（氨基甲酸酯-甲基丙烯酸酯）：合成，透明，热和机械性能
4. Physical Properties of Poly (urethane-methacrylate)s Plastic Sheets Produced from Different Polyols [C] . Lijun Gao, Liming Zhou, Shaoming Fang, Advanced Polymer Processing International Forum . 2010

机译：不同多元醇生产的聚（氨基甲酸酯 - 甲基丙烯酸酯）塑料片的物理性质
5. Hydrophilic Polymers of Poly (2-Hydroxy Ethyl Methacrylate) with Tunable Properties for Drug Release, Sequestration of Blistering Agent, Preparation of Ultra-Strong Hydrogels & Thermal Stability of Various Organic Azides [D] . Ananthoji, Ramakanth. 2012

机译：具有可调节的药物释放特性，螯合起泡剂，超强水凝胶的制备以及各种有机叠氮化物的热稳定性的可调节性质的聚（2-甲基丙烯酸羟乙酯）的亲水性聚合物
6. Construction of NIR Light Controlled Micelles with Photothermal Conversion Property: Poly(poly(ethylene glycol)methyl ether methacrylate) (PPEGMA) as Hydrophilic Block and Ketocyanine Dye as NIR Photothermal Conversion Agent [O] . Lan Yao, Haihui Li, Kai Tu, 2020

机译：具有光热转换性的NIR光控胶束的构建：聚（聚（乙二醇）甲基醚甲基丙烯酸酯）（PPEGMA）作为亲水性嵌段和酮氰胺染料作为NIR光热转化剂
7. Synthesis, structure and properties of poly(ether-urethane)s synthesized using a tri-functional oxypropylated glycerol as a polyol [O] . Janusz Datta, Paulina Kosiorek, Marcin Włoch 2016

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8. DILUTE SOLUTION PROPERTIES OF HIGH-MOLECULAR-WEIGHT POLY (ISOBUTYL METHACRYLATE) I. VISCOSITY IN METHYL ETHYL KETONE [R] . Richard J. Valles, Eleanor C. Schramm, James Stout 1964

机译：高分子量聚（甲基丙烯酸异丁酯）的稀溶液性质I.甲基乙基酮的粘度

Formulation/property relationships in radiation-cured poly(urethane methacrylate) pressure-sensitive adhesives. I. Incorporation of hydrophilic polyols

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