PREPARATION AND PROPERTIES OF NEW POLYCYCLIC ALIPHATIC POLYAMIDES BASE ON DIAMANTANE

Chern YT.; Chung MA.; Fang JS.

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PREPARATION AND PROPERTIES OF NEW POLYCYCLIC ALIPHATIC POLYAMIDES BASE ON DIAMANTANE

机译：基于金刚烷的新型多环脂族聚酰胺的制备及性能

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A series of novel polycyclic aliphatic polyamides was synthesized by direct polycondensation of the 1,6-diamantane dicarboxylic acid with various alicyclic diamines in N-methyl-2-pyrrolidone (NMP) containing lithium chloride, using triphenyl phosphite and pyridine as a condensing agent. The polyamides had inherent viscosities of 0.33-0.49 dL/g. The glass transition temperatures of the these polyamides were in the range of 200-220 degrees C, and the 5% weight loss temperatures were in the range were 290-319 degrees C in nitrogen. (C) 1995 John Wiley & Sons, Inc. [References: 23]

机译：使用亚磷酸三苯酯和吡啶作为缩合剂，通过将1,6-二金刚烷二羧酸与各种脂环族二胺在含氯化锂的N-甲基-2-吡咯烷酮（NMP）中直接缩聚，合成了一系列新型多环脂族聚酰胺。聚酰胺的固有粘度为0.33-0.49dL / g。这些聚酰胺的玻璃化转变温度在氮气中为200-220℃，并且5％失重温度为290-319℃。（C）1995 John Wiley＆Sons，Inc. [参考：23]

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《Journal of Applied Polymer Science》 |1995年第9期|共6页
作者
Chern YT.; Chung MA.; Fang JS.;
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正文语种 eng
中图分类高分子化学（高聚物）;高分子化合物产品;有机化学;
关键词
Vapor-deposition polymerization; N-phosphonium salts; Aromatic polyamides; Carbonylation; Phosphites; Polyimides; Pyridines; Diamines;

机译：气相沉积聚合;N-on盐;芳族聚酰胺;羰基化;亚磷酸酯;聚酰亚胺;吡啶;二胺;

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专利

1. PREPARATION AND PROPERTIES OF NEW POLYCYCLIC ALIPHATIC POLYAMIDES BASE ON DIAMANTANE [J] . Chern YT., Chung MA., Fang JS. Journal of Applied Polymer Science . 1995,第9期

机译：基于金刚烷的新型多环脂族聚酰胺的制备及性能
2. High alpha transitions of new polyamides based on diamantane [J] . Chern YT., Wang WL. Journal of Polymer Science, Part A. Polymer Chemistry . 1998,第8期

机译：基于金刚烷的新型聚酰胺的高α转变
3. Transmission of electronic substituent effects through cage polycyclic alkanes: a computational study of diamantane derivatives based on structural variation [J] . Anna Rita Campanelli, Aldo Domenicano Structural Chemistry . 2014,第2期

机译：通过笼型多环烷烃传递电子取代基效应：基于结构变化的金刚烷衍生物的计算研究
4. Preparation and Properties of Novel In-situ Composite Materials Based on Polyethylene-Polyamide Oriented Blends [C] . Nadya Dencheva, Maria Jovita Oliveira, Olga Carneiro, Advanced Materials Forum IV . 2008

机译：基于聚乙烯-聚酰胺定向共混物的新型原位复合材料的制备与性能
5. I. The preparation and physical properties of crystalline lithium-alkyls. II. The integrated intensity of the infrared absorption band due to O-H stretching in aliphatic alcohols. [D] . Brown, Theodore L. 1956

机译：I.结晶锂-烷基的制备和物理性质。二。脂肪族醇中O-H拉伸引起的红外吸收带的积分强度。
6. The Effect of the Preparation Method and the Dispersion and Aspect Ratio of CNTs on the Mechanical and Electrical Properties of Bio-Based Polyamide-410/CNT Nanocomposites [O] . Itziar Otaegi, Nora Aranburu, Maider Iturrondobeitia, 2019

机译：制备方法以及碳纳米管的分散度和纵横比对生物基聚酰胺-410 / CNT纳米复合材料的机械和电学性能的影响
7. The Effect of the Preparation Method and the Dispersion and Aspect Ratio of CNTs on the Mechanical and Electrical Properties of Bio-Based Polyamide-4,10/CNT Nanocomposites [O] . Itziar Otaegi, Nora Aranburu, Maider Iturrondobeitia, 2019

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8. Rheological and Optical Properties Investigation of Aliphatic (Nylon-66,P(gamma)BLG) And Aromatic KEVLAR(R), NOMEX(R) Polyamide Solutions. [R] . Akoki, H., White, J. L., Fellers, J. F. 1978

机译：脂肪族（尼龙-66，p（γ）BLG）和芳香族KEVLaR（R），NOmEX（R）聚酰胺溶液的流变学和光学性质研究。

PREPARATION AND PROPERTIES OF NEW POLYCYCLIC ALIPHATIC POLYAMIDES BASE ON DIAMANTANE

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