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Migration Behaviors of Antiozonants in Binary Rubber-Based Vulcanizates of NR,SBR,and BR

机译:抗臭氧剂在NR,SBR和BR的二元橡胶基硫化物中的迁移行为

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Influence of rubber composition on migration of N-phenyl-N'-isopropyl-p-phenylenediamine (IPPD),and N-phenyl-N'-(1,3-dimethylbutyl)-p-phenylenediamine (HPPD) to the surface in binary rubber-based vulcanizates of natural rubber (NR),styrene-butadiene rubber (SBR),and butadiene rubber (BR) was studied.Migration experiments were performed at 60 and 80 deg C for 21 days and outdoors for 4 months.Migration rates of IPPD and HPPD in the vulcanizates of SBR/NR and BR/NR blends outdors increased by decreasing the content of NR,and those in the vulcanizates of BR/SBR blends decreased with an increase of the content of BR.Migration behaviors of the antiozonants in the vulcanizates of SBR/NR and BR/NR blends at 60 and 80 deg C,on the whole,showed trends similar to the outdoor results.Migration rates of the antiozonants in the vulcanizates of BR/SBR blends at 60 and 80 deg C showed some differences.Variation of migration behaviors of the antiozoants in the binary rubber-based vulcanizates depending on rubber composition was explained by the interface between dissimilar rubbers and the intermolecular interactions between the matrices and the antiozonants.
机译:橡胶组成对N-苯基-N'-异丙基-对苯二胺(IPPD)和N-苯基-N'-((1,3-二甲基丁基)-对苯二胺(HPPD)迁移到二元表面的影响研究了天然橡胶(NR),丁苯橡胶(SBR)和丁二烯橡胶(BR)的橡胶基硫化胶,分别在60和80摄氏度下进行了21天的迁移实验,并在室外进行了4个月的迁移实验。 SBR / NR和BR / NR共混物硫化橡胶中IPPD和HPPD随NR含量的降低而增加,而BR / SBR共混物硫化橡胶中的IPPD随着BR含量的增加而降低。总体上,在60和80摄氏度下SBR / NR和BR / NR混合物的硫化橡胶显示出与室外结果相似的趋势。在60和80摄氏度下BR / SBR混合物的硫化橡胶中抗臭氧剂的迁移速率表明在二元橡胶基硫化胶中,抗生剂迁移行为的变化。关于橡胶组成的解释是通过不同橡胶之间的界面以及基体与抗臭氧剂之间的分子间相互作用来解释的。

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