Effect of Surface Oxidation of Filler and Silane Coupling Agent on the Chemorheological Behavior of Epoxidized Natural Rubber Filled with ISAF Carbon Black

Manna Aiay K. Bhattacharyya A.K.; De P.P.; Peiffer Dennis G.

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Effect of Surface Oxidation of Filler and Silane Coupling Agent on the Chemorheological Behavior of Epoxidized Natural Rubber Filled with ISAF Carbon Black

机译：填料和硅烷偶联剂的表面氧化对填充ISAF炭黑的环氧天然橡胶化学流变行为的影响。

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On the basis of measurements of physical properties and solvent swelling of the extrudates,it has been observed that epoxidized natural rubber (ENR) interacts chemically with intermediate super abrasion furnace (ISAF) carbon black when the mix of the two was extruded at 130-160degC in a Mosanto Processability Tester (MPT).The extent of interaction between the rubber and filler depends on the following factors:extrusion time,carbon black loading,shear rate,and the extent of oxidation on the carbon black surface.Addition of the silane coupling agent,namely,N-3-(N-vinyl benzyl amino)ethyl-#gamma#-amino propyl trimethoxy silane monohydrochloride,enhances the rate of the interaction.

机译：根据挤出物的物理性能和溶剂溶胀度的测量，已经观察到当两者的混合物在130-160℃下挤出时，环氧化天然橡胶（ENR）与中间超级磨料炉（ISAF）炭黑发生化学相互作用。在Mosanto加工性测试仪（MPT）中，橡胶与填料之间的相互作用程度取决于以下因素：挤出时间，炭黑负载量，剪切率以及炭黑表面上的氧化程度。硅烷偶联剂的添加试剂，即N-3-（N-乙烯基苄基氨基）乙基-γ-氨基丙基三甲氧基硅烷单盐酸盐，提高了相互作用的速率。

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《Journal of Applied Polymer Science》 |1999年第4期|共7页
作者
Manna Aiay K. Bhattacharyya A.K.; De P.P.; Peiffer Dennis G.;
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正文语种 eng
中图分类高分子化学（高聚物）;高分子化合物产品;有机化学;
关键词
expoxidizes natural rubber; surface oxidized carbon black; chemorheol-ogy; extrusion; silane coupling agent; chemical interaction;

机译：氧化天然橡胶;表面氧化的炭黑;化学酚醛胶;挤出;硅烷偶联剂;化学相互作用;

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1. Effect of Surface Oxidation of Filler and Silane Coupling Agent on the Chemorheological Behavior of Epoxidized Natural Rubber Filled with ISAF Carbon Black [J] . Manna Aiay K. Bhattacharyya A.K., De P.P., Peiffer Dennis G. Journal of Applied Polymer Science . 1999,第4期

机译：填料和硅烷偶联剂的表面氧化对填充ISAF炭黑的环氧天然橡胶化学流变行为的影响。
2. EFFECT OF HAF CARBON BLACK FILLER ON CHEMORHEOLOGICAL BEHAVIOR OF POLY(ACRYLIC ACID) EPOXIDIZED NATURAL RUBBER BLEND [J] . Mallick A., Gupta BR., Tripathy DK., Journal of Applied Polymer Science . 1997,第1期

机译：HAF炭黑填料对聚丙烯酸交联氧化天然橡胶混合料化学流变行为的影响
3. Effect of silane coupling agent on the chemorheological behaviour of epoxidised natural rubber filled with precipitated silica [J] . Manna AK., De PP., Tripathy DK., Polymer: The International Journal for the Science and Technology of Polymers . 1998,第26期

机译：硅烷偶联剂对填充有沉淀二氧化硅的环氧化天然橡胶化学流变行为的影响
4. Optimization of Epoxidation Degree and Silane Coupling Agent Content for Silica-Filled Epoxidized Natural Rubber Tire Tread Compounds [C] . Wisut Kaewsakul, Kannika Sahakaro, Wilma K. Dierkes Asia Pacific Rubber Conference . 2014

机译：二氧化硅填充环氧化天然橡胶轮胎胎面化合物对环氧化度和硅烷偶联剂含量的优化
5. NMR studies of carbon black filled, accelerated sulfur-vulcanization of natural rubber and cis-polyisoprene. [D] . Mori, Makio. 1997

机译：核磁共振研究炭黑填充，加速天然橡胶和顺式聚异戊二烯的硫磺硫化。
6. Reinforcing Behaviors of Sulfur-Containing Silane Coupling Agent in Natural Rubber-Based Magnetorheological Elastomers with Various Vulcanization Systems [O] . Mengxin Wang, Xiaoqian Hao, Wenju Wang 2020

机译：具有各种硫化系统的天然橡胶基磁流变弹性体中含含硫硅烷偶联剂的行为
7. Effects of TESPT-Silane Coupling Agent on Torque Properties and Degree of Filler Dispersion of Silica Filled Natural Rubber and Epoxidized Natural Rubbers Compounds [O] . Indra Surya, Nabil Hayeemasae 2019

机译：硅烷偶联剂对二氧化硅填充天然橡胶和环氧化天然橡胶化合物的扭矩性质对扭矩性质的影响及填料分散体

Effect of Surface Oxidation of Filler and Silane Coupling Agent on the Chemorheological Behavior of Epoxidized Natural Rubber Filled with ISAF Carbon Black

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