首页> 外文期刊>Journal of Applied Polymer Science >Preparation and solid-state nuclear magnetic resonance characterization a styrene/butadiene/acrylonitrile (ABS/poly(vinyl chloride) (PVC)/gypsum ternary system
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Preparation and solid-state nuclear magnetic resonance characterization a styrene/butadiene/acrylonitrile (ABS/poly(vinyl chloride) (PVC)/gypsum ternary system

机译:苯乙烯/丁二烯/丙烯腈(ABS /聚氯乙烯(PVC)/石膏三元体系)的制备和固态核磁共振表征

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摘要

Polymer blends were prepared to obtain a new material with specific characteristics. To prepare a miscible polymer blend, it is necessary to evaluate the chemical structure and molecular dynamics of all polymers involved and to thereby establish a structure-property relationship for these materials. In this work, ternary blends for application in plates chromatography were formed with styrene/butadiene/acrylinotrile (ABS), poly(vinyl chloride) (PVC), and gypsum, and were studied by solid-state carbon-13 nuclear magnetic resonance (C-13 NMR). Magic-angle spinning (MAS), cross-polarization magic-angle spinning (CP-MAS), variable contact time (VCT), and proton spin-lattice relation time in the rotating frame (T(1)(H)rho) were the techniques used to evaluate the miscibility, homogeneity, and compatibility of polymer blends at the molecular level. From the values of T(1)(H)rho, it was verified that ABS/PVC/gypsum formed good polymer blends with some specific physical interaction at the molecular level. (C) 2003 Wiley Periodicals, Inc. [References: 16]
机译:制备聚合物共混物以获得具有特定特性的新材料。为了制备可混溶的聚合物共混物,有必要评估所有涉及的聚合物的化学结构和分子动力学,从而建立这些材料的结构-性质关系。在这项工作中,用苯乙烯/丁二烯/丙烯腈(ABS),聚氯乙烯(PVC)和石膏形成了用于板色谱的三元共混物,并通过固态碳13核磁共振(C -13 NMR)。魔角旋转(MAS),交叉极化魔角旋转(CP-MAS),可变接触时间(VCT)和旋转框架中的质子自旋晶格关系时间(T(1)(H)rho)为用于评估聚合物共混物在分子水平上的混溶性,均质性和相容性的技术。从T(1)(H)rho的值可以证明,ABS / PVC /石膏形成了良好的聚合物共混物,在分子水平上具有某些特定的物理相互作用。 (C)2003 Wiley Periodicals,Inc. [参考:16]

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