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Compatibility study of natural rubber and ethylene-propylene-diene rubber blends

机译:天然橡胶与乙烯-丙烯-二烯橡胶混合物的相容性研究

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The compatibility of natural rubber/ethylene-propylene-diene monomer (EPDM) blends with and without different compatibilizers was evaluated with viscosity measurements, differential scanning calorimetry, and scanning electron microscopy. The blends were modified with two methods. In the first method, high-energy radiation, in the form of gamma-rays, was used to create crosslinks (chemical bonds) between the rubber chains at the domain boundaries. In the second method, various compatibilizers, such as ethylene-propylene-diene monomer-g-maleic anhydride (prepared by the radiation-induced graft copolymerization of EPDM with maleic anhydride), polybutadiene rubber, chlorinated rubber, chlorosulfonated polyethylene, and poly(vinyl chloride), were used. The results revealed that the addition of a small percentage of a compatibilizer reduced the domain size of the dispersed phase. Furthermore, the compatibility and properties of the blends were greatly enhanced and improved. (C) 2003 Wiley Periodicals, Inc. [References: 30]
机译:用粘度测量,差示扫描量热法和扫描电子显微镜评价天然橡胶/乙烯-丙烯-二烯单体(EPDM)共混物在有和没有不同增容剂的情况下的相容性。共混物用两种方法改性。在第一种方法中,使用伽马射线形式的高能辐射在域边界处的橡胶链之间产生交联键(化学键)。在第二种方法中,各种增容剂,例如乙烯-丙烯-二烯单体-g-马来酸酐(通过辐射诱导的EPDM与马来酸酐的接枝共聚制备),聚丁二烯橡胶,氯化橡胶,氯磺化聚乙烯和聚(乙烯基)氯化物)。结果表明,添加少量的增容剂会减小分散相的畴尺寸。此外,共混物的相容性和性能大大提高和改善。 (C)2003 Wiley Periodicals,Inc. [参考:30]

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