Free radical co- and terpolymerization of styrene, hydrogenated cardanyl acrylate, and cardanyl acetate

Nguyen LH.; Koerner H.; Lederer K.

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Free radical co- and terpolymerization of styrene, hydrogenated cardanyl acrylate, and cardanyl acetate

机译：苯乙烯，氢化丙烯酸氧丙烯酯和乙酸氧乙烯酯的自由基共聚和三元聚合

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Hydrogenated cardanyl acrylate (HCA) and cardanyl acetate (CAGE) were synthesized from cardanol. The copolymerizations of HCA, CACE, and styrene (S) with methyl ethyl ketone peroxide (MEKP) and cobalt salt as the initiator were studied by FTIR. Based on FTIR results the reactivity ratios of the three copolymerization systems S-HCA, S-CACE, and HCA-CACE were determined by three different methods (Mayo-Lewis, Fineman-Ross, and Kelen-Tudos). Results obtained from the three methods are in good agreement. Instantaneous compositions and composition shift as a function of conversion is calculated for the S-HCA-CACE system with different feed compositions. (C) 2003 Wiley Periodicals, Inc. [References: 17]

机译：由腰果酚合成了氢化丙烯酸腰果酚酯（HCA）和醋酸腰果酚酯（CAGE）。通过FTIR研究了HCA，CACE和苯乙烯（S）与甲基乙基酮过氧化物（MEKP）和钴盐作为引发剂的共聚。基于FTIR结果，通过三种不同的方法（Mayo-Lewis，Fineman-Ross和Kelen-Tudos）确定了三种共聚体系S-HCA，S-CACE和HCA-CACE的反应率。从这三种方法获得的结果非常吻合。对于具有不同进料组成的S-HCA-CACE系统，计算了瞬时组成和组成随转化率的变化。（C）2003 Wiley Periodicals，Inc. [参考：17]

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《Journal of Applied Polymer Science》 |2003年第6期|共11页
作者
Nguyen LH.; Koerner H.; Lederer K.;
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正文语种 eng
中图分类高分子化学（高聚物）;
关键词
Copolymerization; Ftir; Kinetics; Cardanyl; Polymerization; Methacrylate;

机译：共聚;Ftir;动力学;Cardanyl;聚合;甲基丙烯酸酯;

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1. Free radical co- and terpolymerization of styrene, hydrogenated cardanyl acrylate, and cardanyl acetate [J] . Nguyen LH., Koerner H., Lederer K. Journal of Applied Polymer Science . 2003,第6期

机译：苯乙烯，氢化丙烯酸氧丙烯酯和乙酸氧乙烯酯的自由基共聚和三元聚合
2. Bulk Free-Radical Co- and Terpolymerization of n-Butyl Acrylate/2-Ethylhexyl Acrylate/Methyl Methacrylate [J] . Gabriel Vida A., Dube Marc A. Macromolecular reaction engineering . 2019,第2期

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3. N-oxyl mediated free radical donor-acceptor co- and terpolymerization of styrene, cyclic maleimide monomers and n-butyl methacrylate [J] . Butz S., Schmidt-Naake G., Baethge H. Macromolecular chemistry and physics . 2000,第16期

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机译：丙烯酸正丁酯，甲基丙烯酸甲酯和丙烯酸2-乙基己酯的共聚和三聚反应活性比估算
5. A Comprehensive Kinetic Model for High Temperature Free Radical Production of Styrene/Methacrylate/Acrylate Resins. [D] . Wang, Wei. 2010

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6. Copper mediated controlled radical copolymerization of styrene and 2-ethylhexyl acrylate and determination of their reactivity ratios [O] . Bishnu P. Koiry, Nikhil K. Singha 2014

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7. Determination of the Free Radical Concentration Ratio in the Copolymerization of Methyl Acrylate and Styrene. Application of Radical Trapping and 15N NMR Spectroscopy [O] . -1

机译：丙烯酸甲酯和苯乙烯共聚的自由基浓度比的测定。自由基诱捕和15N NMR光谱的应用

Free radical co- and terpolymerization of styrene, hydrogenated cardanyl acrylate, and cardanyl acetate

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