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首页> 外文期刊>Journal of Applied Polymer Science >Development of new concepts for the control of polymerization processes: Multiobjective optimization and decision engineering. I. Application to emulsion homopolymerization of styrene
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Development of new concepts for the control of polymerization processes: Multiobjective optimization and decision engineering. I. Application to emulsion homopolymerization of styrene

机译:开发用于控制聚合过程的新概念:多目标优化和决策工程。一,苯乙烯乳液均聚的应用

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This article deals with the development of a multicriteria analysis, and its application to the optimization of batch emulsion polymerization processes. This new approach in the domain of polymer reaction engineering illustrates how a multiobjective optimization aided by a genetic algorithm and using the Pareto concept of domination is useful. In this process (emulsion homopolymerization of styrene), several objectives were simultaneously required, e.g., a high quality of the resulting products together with a high productivity. The aim of this study was to find the optimal experimental conditions to obtain simultaneously the minimum reaction time and designed values for both average molecular weights and particles size. To do that, an adapted mathematical model, able to describe all the process physicochemical phenomena, was been first elaborated. The multicriteria analysis then gave a set of nondominated points with conflicting criteria. A decision support system was then developed and applied to rank the Pareto solutions set and to propose some good solutions by taking into account the decision maker's preferences. (C) 2003 Wiley Periodicals, Inc. J Appl Polym Sci 87: 2383-2396, 2003. [References: 35]
机译:本文涉及多标准分析的发展,及其在间歇式乳液聚合工艺优化中的应用。这种在聚合物反应工程领域中的新方法说明了如何借助遗传算法并使用Pareto控制概念来进行多目标优化。在该方法(苯乙烯的乳液均聚)中,同时需要多个目的,例如,所得到的产物的高质量和高生产率。这项研究的目的是找到最佳的实验条件,以同时获得最短的反应时间和平均分子量和粒径的设计值。为此,首先阐述了一个能够描述所有过程物理化学现象的适应性数学模型。然后,多标准分析给出了一组具有冲突标准的非支配点。然后开发了决策支持系统,并将其用于对Pareto解决方案集进行排名,并通过考虑决策者的偏好来提出一些好的解决方案。 (C)2003 Wiley Periodicals,Inc. J Appl Polym Sci 87:2383-2396,2003。[参考:35]

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