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Effects of lignin as a filler on properties of soy protein plastics. 1. Lignosulfonate

机译:木质素作为填料对大豆蛋白塑料性能的影响。 1.木质素磺酸盐

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A series of biodegradable plastics from soy protein isolate (SPI) and lignosulfonate (LS) with a weight ratio of 0:10 to 6:4 were prepared with 40 wt % glycerol as a plasticizer by compression molding. Their properties were investigated by wide-angle X-ray diffraction (WAXD), differential scanning calorimetry (DSC), dynamical mechanical thermal analysis (DMTA), scanning electron microscopy (SEM), and tensile tests. The results indicated that the introduction of a moderate LS content from 30 to 40 parts in the blends could simultaneously enhance the tensile strength, elongation, and Young's modulus of soy protein plastics alone. Studies of the water sensitivity of the materials suggested that the strong interaction between LS and SPI could restrict the effect of water on the swelling and the damage of the materials, resulting in lower water absorption. The improvement of the properties was attributed mainly to the existence of the beneficial microphase separation and the formation of crosslinked structures because of the introduction of LS into soy protein plastics. Therefore, a model of a crosslinked network formed from SPI molecules with an LS center was established based on the existence of strong physical interactions between LS and SPI. (C) 2003 Wiley Periodicals, Inc. [References: 20]
机译:通过压缩成型,以40重量%的甘油作为增塑剂,制备了重量比为0:10至6:4的大豆分离蛋白(SPI)和木质素磺酸盐(LS)的一系列可生物降解的塑料。通过广角X射线衍射(WAXD),差示扫描量热法(DSC),动态机械热分析(DMTA),扫描电子显微镜(SEM)和拉伸试验研究了它们的性能。结果表明,在掺混物中引入30到40份适中的LS含量可以同时提高单独大豆蛋白塑料的拉伸强度,伸长率和杨氏模量。对材料的水敏感性的研究表明,LS和SPI之间的强相互作用可能会限制水对材料的溶胀和破坏的影响,从而降低吸水率。性能的改善主要归因于将LS引入大豆蛋白塑料中,有利的微相分离的存在和交联结构的形成。因此,基于LS和SPI之间存在强烈的物理相互作用,建立了由具有LS中心的SPI分子形成的交联网络模型。 (C)2003 Wiley Periodicals,Inc. [参考:20]

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