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Piperazine-Based Homo- and Copolymers Containing Trivalent and Quaternary Nitrogen Functionalities

机译:含三价和季氮官能团的哌嗪基均聚物和共聚物

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摘要

The synthesis and solution properties of poly(1,1,-diallyl-4-hydropiperazinedichloride)[poly(DAHPD)](3),a dicationic polymer,and poly(1,1-diallylpiperaziniumchloride),[poly(DAPC)](4),a bifunctional polymer with trivalent and quaternary nitrogens,and their corresponding copolymers with sulfur dioxide,poly(DAHPD-SO_2)(6)and poly(DAPC-SO_2)(7),are discussed.Dicationic polymers(3) and (6) were found to have less pronounced polyelectrolyte effects than their monocationic counterparts(4) and (7).
机译:聚(1,1,-diallyl-4-hydropiperazinedichloride)[poly(DAHPD)](3)和聚(1,1-diallylpiperaziniumchloride),[poly(DAPC)]()的合成及溶液性质4),讨论了具有三价和季氮的双功能聚合物,以及它们与二氧化硫的相应共聚物,聚(DAHPD-SO_2)(6)和聚(DAPC-SO_2)(7)。阳离子聚合物(3)和( 6)被发现比单阳离子对应物(4)和(7)具有更不明显的聚电解质效应。

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