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Studies of novel water-soluble colored polyesters containing azo moiety

机译:含偶氮部分的新型水溶性彩色聚酯的研究

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A series of water-soluble colored polyesters (polymeric dyes) were synthesized by interfacial polycondensation reaction of terephthaloyl chloride and various bisazodiols (monomeric dyes) that were derived from diarylidene cyclopentanone and diarylidene cyclohexanone by coupling with various diazonium salts of anthraquinone dyes containing the sodium salts of the sulfonic acid group. All the colored polyesters were characterized by their elemental analysis, IR and UV-visible spectroscopy, viscometry, solubility, and TGA. Color and dyeability of the polymeric dyes are discussed by comparing them with those of the corresponding monomeric dyes. The color fastness of the polymeric dyes show fair to very good fastness to Light and very good to excellent fastness to washing, rubbing, perspiration, and sublimation. (C) 1998 John Wiley & Sons, Inc. [References: 24]
机译:通过对苯二甲酰氯与衍生自二亚芳基环戊酮和二芳基环己酮的各种双偶氮二醇(单体染料)的界面缩聚反应,通过与含有钠盐的蒽醌染料的各种重氮盐偶合,合成了一系列水溶性有色聚酯(聚合染料)磺酸基团。所有有色聚酯均通过其元素分析,红外和紫外可见光谱,粘度测定法,溶解度和TGA进行表征。通过将聚合物染料与相应的单体染料的颜色和可染性进行比较来讨论它们。聚合物染料的色牢度显示出对光的牢度至非常好,对洗涤,摩擦,汗渍和升华的牢度也非常好。 (C)1998 John Wiley&Sons,Inc. [参考:24]

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