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Fracture Mechanisms in Preformed Polyphenylene Oxide Particle-Modified Bismaleimide Resins

机译:预制聚苯醚颗粒改性双马来酰亚胺树脂的断裂机理

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摘要

Fracture toughness and failure mechanisms in preformed poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) particle-modified bismaleimide (BMI) systems are investigated.The fracture toughness of BMI can be significantly improved by incoporating preformed PPO particles without causing significant deteroration in other mechanical and thermal properties.The fracture mechanisms in BMI/PPO appear to be dominated by craze-like damage.Further investigatio of the craze-like damage zone using transmission electron microscopy reveals that crazes are formed inside the PPO particle phase and dilatation bands,which appear to be triggered by the crazes inside the PPO particle,are formed in the BMI matrix.Particle bridging is also found to contribute to the toughening of BMI/PPO.The benefits of using preformed PPO particles to toughen BMI and other brittle thermosets for composite and adhesive applications are discussed.
机译:研究了预成型的聚(2,6-二甲基-1,4-苯撑氧)(PPO)改性双马来酰亚胺(BMI)体系的断裂韧性和破坏机理,通过掺入预成型的PPO颗粒可以显着提高BMI的断裂韧性BMI / PPO的断裂机制似乎由裂纹状的破坏占主导地位。使用透射电镜进一步研究裂纹状的破坏区域,发现裂纹在PPO颗粒内部形成在BMI基质中形成了由PPO颗粒内部的裂纹触发的相带和膨胀带。还发现颗粒桥接有助于BMI / PPO的增韧。使用预制的PPO颗粒使BMI增韧的好处讨论了用于复合材料和粘合剂应用的其他脆性热固性材料。

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