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Acrylonitrile-butadiene-styrene toughened nylon 6: The influences of compatibilizer on morphology and impact properties

机译:丙烯腈-丁二烯-苯乙烯增韧尼龙6:增容剂对形态和冲击性能的影响

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摘要

Polymer alloys have been used as an alternative to obtain polymeric materials with unique physical properties. Generally, the polymer mixture is incompatible, which makes it necessary to use a compatibilizer to improve the interfacial adhesion. Nylon 6 (PA6) is an attractive polymer to use in engineering applications, but it has processing instability and relatively low notched impact strength. In this study, the acrylonitrile-butadiene-styrene (ABS) triblock copolymer was used as an impact modifier for PA6. Poly(methyl methacrylate-co-maleic anyhydride) (MMAMA) and poly(methyl methacrylate-co-glycidyl methacrylate) (MMA-GMA) were used as compatibilizers for this blend. The morphology and impact strength of the blends were evaluated as a function of blend composition and the presence of compatibilizers. The blends compatibilized with maleated copolymer exhibited an impact strength up to 800 J/m and a morphology with ABS domains more efi8ciently dispersed. Moderate amounts of MA functionality in the compatibilizer (similar to5%) and small amounts of compatibilizer in the blend (similar to5%) appear sufficient to improve the impact properties and ABS dispersion. (C) 2002 Wiley Periodicals, Inc. [References: 31]
机译:聚合物合金已被用作获得具有独特物理性能的聚合物材料的替代方法。通常,聚合物混合物是不相容的,这使得必须使用相容剂来改善界面粘合性。尼龙6(PA6)是用于工程应用的有吸引力的聚合物,但它具有加工不稳定性和相对较低的缺口冲击强度。在这项研究中,丙烯腈-丁二烯-苯乙烯(ABS)三嵌段共聚物被用作PA6的抗冲改性剂。聚(甲基丙烯酸甲酯-共马来酸酐)(MMAMA)和聚(甲基丙烯酸甲酯-共丙烯酸甲基丙烯酸缩水甘油酯)(MMA-GMA)用作该共混物的增容剂。根据共混物的组成和相容剂的存在来评估共混物的形态和冲击强度。与马来酸化共聚物相容的共混物显示出高达800 J / m的冲击强度,并且具有更有效分散的ABS域的形态。增容剂中适量的MA功能(约5%)和共混物中的少量增容剂(约5%)似乎足以改善抗冲击性能和ABS分散性。 (C)2002 Wiley Periodicals,Inc. [参考:31]

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