首页> 外文期刊>Journal of Applied Polymer Science >Resin-transfer molding of natural fiber-reinforced plastic. I. Kinetic study of an unsaturated polyester resin containing an inhibitor and various promoters
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Resin-transfer molding of natural fiber-reinforced plastic. I. Kinetic study of an unsaturated polyester resin containing an inhibitor and various promoters

机译:天然纤维增强塑料的树脂传递模塑。 I.含有抑制剂和各种促进剂的不饱和聚酯树脂的动力学研究

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In this study an autocatalytic model was used to describe the cure of a polyester system containing various promoters and an inhibitor. The effect of the initiator concentration was investigated. Isothermal DSC measurements were used to determine the kinetic parameters for the curing reaction. The rate of curing increased with increasing initiator concentration. The parameters were found to be temperature dependent. The nonlinear regression analysis showed that by fixing one parameter at a constant value the temperature dependency of the other parameters was described by simple relationships. The model was then compared to the experimental data. The reaction rate could be predicted fairly well in a wide range of temperatures. These results will be used to model the cure of this resin in a resin transfer-molding (RTM) process. (C) 2003 Wiley Periodicals, Inc. [References: 16]
机译:在这项研究中,使用自动催化模型来描述含有各种促进剂和抑制剂的聚酯体系的固化。研究了引发剂浓度的影响。等温DSC测量用于确定固化反应的动力学参数。固化速率随引发剂浓度的增加而增加。发现参数与温度有关。非线性回归分析表明,通过将一个参数固定为常数,可以通过简单关系描述其他参数的温度依赖性。然后将模型与实验数据进行比较。可以在很宽的温度范围内很好地预测反应速率。这些结果将用于在树脂传递成型(RTM)过程中对该树脂的固化进行建模。 (C)2003 Wiley Periodicals,Inc. [参考:16]

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