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Nuclear magnetic resonance studies of N-vinylcarbazole/methyl methacrylate copolymers

机译:N-乙烯基咔唑/甲基丙烯酸甲酯共​​聚物的核磁共振研究

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摘要

Copolymers of N-vinylcarbazole and methyl methacrylate of different compositions were prepared by solution polymerization with azobisisobutyronitrile as an initiator, and their compositions were determined from quantitative C-13{H-1}-NMR spectroscopy. The reactivity ratios for the comonomers were calculated with the Kelen-Tudos and nonlinear error-in-variable methods. The complete spectral assignment of the overlapping H-1 and C-13{H-1} spectra of the copolymers was made with the help of distortionless enhancement by polarization transfer, two-dimensional heteronuclear single-quantum correlation, and total correlation spectroscopy. (C) 2003 Wiley Periodicals, Inc. [References: 16]
机译:以偶氮二异丁腈为引发剂,通过溶液聚合制备了N-乙烯基咔唑和甲基丙烯酸甲酯的共聚物,并通过定量C-13 {H-1} -NMR光谱确定了其组成。共聚单体的反应率是用Kelen-Tudos和非线性可变误差方法计算的。借助于偏振转移,二维异核单量子相关性和全相关性光谱的无畸变增强,完成了共聚物的H-1和C-13 {H-1}重叠光谱的完整光谱分配。 (C)2003 Wiley Periodicals,Inc. [参考:16]

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