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首页> 外文期刊>Journal of Applied Polymer Science >ELECTRICAL PROPERTIES OF BLOCK COPOLYMERS CONTAINING SILVER NANOCLUSTERS WITHIN ORIENTED LAMELLAR MICRODOMAINS
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ELECTRICAL PROPERTIES OF BLOCK COPOLYMERS CONTAINING SILVER NANOCLUSTERS WITHIN ORIENTED LAMELLAR MICRODOMAINS

机译：定向微区中含银纳米簇的嵌段共聚物的电学性质

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摘要

Films containing silver nanoclusters within a lamellar morphology were obtained via postprocessing reduction of the silver-containing regions of block copolymers synthesized by ring opening metathesis polymerization. Solution-cast films (0.1 mm thickness) of the block copolymer exhibited an oriented lamellar morphology with lamellar normals perpendicular to the film plane. The slightly anisotropic dielectric properties, perpendicular and parallel to the film plane, were investigated by direct measurement and by model calculations. The conductivity was highly anisotropic, differing by at least four orders of magnitude in directions parallel and perpendicular to the film plane. (C) 1997 John Wiley & Sons, Inc. [References: 19]
机译：通过后处理还原通过开环易位聚合合成的嵌段共聚物的含银区域，获得了具有层状形态的银纳米簇的薄膜。嵌段共聚物的溶液流延膜（0.1毫米厚）表现出定向的层状形态，层状法线垂直于膜平面。通过直接测量和模型计算研究了垂直于膜平面和平行于膜平面的稍微各向异性的介电性质。电导率是高度各向异性的，在平行于膜平面和垂直于膜平面的方向上相差至少四个数量级。 （C）1997 John Wiley＆Sons，Inc. [参考：19]

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