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Effect of molecular structure in branched polyethylene on adhesion properties with polypropylene

机译:支化聚乙烯中分子结构对与聚丙烯粘合性能的影响

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Adhesion properties between branched polyethylene (PE) and isotactic polypropylene (PP) were studied by a peel test and scanning electron microscopy. In this study, two types of branched PEs were used; one is a linear low density polyethylene (LLDPE) and the other is a high pressure low density polyethylene (LDPE). The adhesive strength of the LLDPE/PP is much higher than that of LDPE/PP. Furthermore, the formation of PE influxes between PP spherulites has a small effect on the adhesion. The dynamic viscoelastic measurements for the binary blends composed of branched PE and PP were also carried out to estimate the interfacial tension by using a rheological emulsion model proposed by Palierne. The interfacial tension is 1.0 mN for LLDPE/PP and 2.1 mN for LDPE/PP, suggesting that the interfacial thickness of LLDPE/PP is about twice that of LDPE/PP. The adhesive strength between branched PE and PP will be determined by the interfacial thickness, which represents the entanglements between two polymers. (C) 1998 John Wiley & Sons, Inc. [References: 21]
机译:通过剥离试验和扫描电子显微镜研究了支链聚乙烯(PE)和全同立构聚丙烯(PP)之间的粘合性能。在这项研究中,使用了两种类型的分支PE。一种是线性低密度聚乙烯(LLDPE),另一种是高压低密度聚乙烯(LDPE)。 LLDPE / PP的粘合强度远高于LDPE / PP。此外,PP球晶之间PE流入的形成对附着力的影响很小。还使用Palierne提出的流变乳液模型,对支链PE和PP组成的二元共混物进行了动态粘弹性测量,以评估界面张力。 LLDPE / PP的界面张力为1.0 mN,而LDPE / PP的界面张力为2.1 mN,表明LLDPE / PP的界面厚度约为LDPE / PP的两倍。支链PE和PP之间的粘合强度将由界面厚度决定,界面厚度代表两种聚合物之间的缠结。 (C)1998 John Wiley&Sons,Inc. [参考:21]

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