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MECHANICAL AND MORPHOLOGICAL PROPERTIES OF ELASTOMER-MODIFIED POLYPROPYLENE/POLYAMIDE-6 BLENDS

机译:弹性体改性的聚丙烯/聚酰胺-6混合料的力学和形态学性能

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摘要

Polypropylene/polyamide-6 (70:30) blends, containing dispersed discrete polyamide-6 microphases as matrix reinforcement, represent attractive materials for engineering applications. In order to enhance impact resistance, ethene/propene (EPM) was incorporated as a second separately dispersed microphase using reactive blending technology. Blend morphologies were controlled by adding maleic-anhydride-grafted-polypropylene (PP-g-MA) as compatibilizer during melt processing, thus enhancing dispersion and interfacial adhesion of the polyamide-6 phase. With PP-g-MA volume fractions increasing from 2.5 to 10 vol %, much finer dispersions of discrete polyamide-6 with average domain sizes decreasing from 8 to 0.8 mu m were obtained. When polyamide-6 and ethene/propene (EPM)-rubber are dispersed simultaneously in the polypropylene matrix, impact resistance was improved. The influence of PP-g-MA volume fraction and blend morphologies on mechanical properties such as Young's modulus, yield stress, notched Charpy impact resistance was investigated. The ternary polypropylene/polyamide-6/EPM blend properties were compared with those of binary polypropylene blends containing the equivalent volume fraction of EPM. (C) 1995 John Wiley and Sons, Inc. [References: 12]
机译:聚丙烯/聚酰胺6(70:30)共混物包含分散的离散聚酰胺6微相作为基质增强材料,是工程应用中有吸引力的材料。为了增强抗冲击性,使用反应混合技术将乙烯/丙烯(EPM)作为第二种单独分散的微相加入。通过在熔融加工过程中添加马来酸酐接枝聚丙烯(PP-g-MA)作为增容剂来控制共混物的形态,从而增强聚酰胺6相的分散性和界面粘合力。随着PP-g-MA的体积分数从2.5体积%增加至10体积%,获得了平均域尺寸从8μm降低至0.8μm的离散聚酰胺-6的更细的分散体。当聚酰胺6和乙烯/丙烯(EPM)橡胶同时分散在聚丙烯基质中时,抗冲击性得到了改善。研究了PP-g-MA的体积分数和共混物形态对机械性能的影响,如杨氏模量,屈服应力,缺口夏比冲击强度。将三元聚丙烯/聚酰胺-6 / EPM共混物的性能与含有等体积EPM的二元聚丙烯共混物的性能进行了比较。 (C)1995 John Wiley and Sons,Inc. [参考:12]

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