• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Journal of Applied Polymer Science >Synthesis and Properties of Novel Perfluorocyclohexylated Compounds with Bis(perfluorocyclohexane carbonyl) Peroxide
【24h】

Synthesis and Properties of Novel Perfluorocyclohexylated Compounds with Bis(perfluorocyclohexane carbonyl) Peroxide

机译：新型双（全氟环己烷羰基）过氧化物全氟环己基化合物的合成与性能

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Bis(perfluorocyclohexane carbonyl) peroxide was prepared by the reaction of the corresponding acyl fluoride and hydrogen peroxide. This peroxide was applied to the preparation of perfluorocyclohexylated end-capped oligomers via a radical process under very mild conditions. In cyclic perfluorocyclohexylated end-capped oligomers containing hydroxy segments, these oligomers could cause a gelation in water and in polar organic solvents such as MeOH, EtOH, dimethylformamide (DMF), and dimethylsulfoxide (DMSO), and the gelling ability of these oligomers was superior to that of the corresponding linear perlfuorooxaalkylated oligomers. Furthermore, perflurooocyclohexylation of polystyrene or benzene was proceeded via a single electron transfer reaction by using this peroxide.
机译：双（全氟环己烷羰基）过氧化物是通过相应的酰基氟与过氧化氢反应制备的。该过氧化物在非常温和的条件下通过自由基过程被用于制备全氟环己基化的封端低聚物。在含有羟基链段的环状全氟环己基化的封端低聚物中，这些低聚物可在水中和极性有机溶剂（如MeOH，EtOH，二甲基甲酰胺（DMF）和二甲基亚砜（DMSO））中引起胶凝，并且这些寡聚物的胶凝能力优异。相应的线性全氟代氧杂烷基化的低聚物。此外，使用该过氧化物通过单电子转移反应进行聚苯乙烯或苯的全氟环己基化。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号