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Wood-Polymer Composites Made with Acrylic Monomers, Isocyanate, and Maleic Anhydride

机译:由丙烯酸单体,异氰酸酯和顺丁烯二酸酐制成的木聚合物复合材料

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摘要

Wodo could provide better service in some applications if it were harder and more dimensionally stable. In this study, wood-polymer composites (WPC) made with different chemical combinations were evaluated for dimensional stability,a bility to exclude water vapor and liquid water,a nd hardness, Pine, maple, and oak solid wood were combined with differnet combinations of hexanediol diacrylate, hydroxyethyl methacrylate, hexamethylene diisocyanate, and maleic anhydride, Treatment slowed the rates of water vapor and liquid water absorption. Although the resultant dimensional stability was not permanent, the rate fo swelling of WPC specimens was less than that of unmodified wood specimens. In addition, WPC were harder than unmodified wood. The chemical combination of hexanediol diacrylate, hydroxyethyl methacrylate, and hexamethylene diisocyanate greatly decreased wetting and penetration of water into the wood. This chemical combination also gave the hardest and most dimensionally stable WPC. In general, WPC prepared using hydroxyethyl methacrylate were harder than specimens made without hydroxyethyl methacrylate and excluded water and moisture more effectively.
机译:如果更硬,尺寸更稳定,Wodo可以在某些应用程序中提供更好的服务。在这项研究中,评估了使用不同化学组合制成的木材-聚合物复合材料(WPC)的尺寸稳定性,排除水蒸气和液态水的能力,硬度,松木,枫木和橡木实木与以下两种不同的组合:己二醇二丙烯酸酯,甲基丙烯酸羟乙酯,六亚甲基二异氰酸酯和马来酸酐,处理减慢了水蒸气和液体吸水率。尽管最终的尺寸稳定性不是永久性的,但WPC样品的溶胀率小于未改性的木材样品。此外,WPC比未改性的木材坚硬。己二醇二丙烯酸酯,甲基丙烯酸羟乙酯和六亚甲基二异氰酸酯的化学结合大大降低了水的润湿和渗透到木材中的能力。这种化学组合还提供了最坚硬,尺寸最稳定的WPC。通常,使用甲基丙烯酸羟乙酯制备的WPC比不使用甲基丙烯酸羟乙酯制备的样品坚硬,并且可以更有效地排除水和水分。

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