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Generation of a Fibrillar Core in PET Fiber by Cold Drawing

机译:通过冷拉伸在PET纤维中生成原纤芯

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Cold draw processing of poly(ethylene terephthalate) yarns has been discovered that yields a sheath/fibrillar core (s/fc) microstructure in the each fiber of a yarn.When aged,unoriented,noncrystalline spun yarns were cold drawn,high(>5.7:1) draw ratios could be achieved and an s/fc microstructure resulted.Cold drawing also generated a high oriented amorphous content.The tensile and shrinkage properties of yarns wiht the s/fc microstructure and high oriented amorphous content were examined as function of processing (drawing,annealing,and relaxing).The microstructure was examined by scanning electron microscopy,transmission electron microscopy,smallangle X-ray scattering,wide-angle X-ray scattering,and optical microscopy.The fibrillar microstructure survives all processing.Management of the oriented amorphous component under heat and tension contributes to the greater stiffness (modulus) and dimensional stability of processed s/fc yarns.The properties of yarns with an s/fc microstructure are compared with more conventional hot drawn yarns.
机译:已经发现,聚对苯二甲酸乙二醇酯纱线的冷拉伸加工会在纱线的每根纤维中产生皮/原纤芯(s / fc)的微观结构。当老化,未取向,非晶态短纤纱线被冷拉伸时,高(> 5.7) 1:1:可以达到拉伸比并形成s / fc微观结构,冷拉伸也产生了高取向的无定形含量,检验了具有s / fc微观结构和高取向的无定形含量的纱线的拉伸和收缩性能(拉伸,退火和松弛)。通过扫描电子显微镜,透射电子显微镜,小角X射线散射,广角X射线散射和光学显微镜检查微观结构。原纤维的微观结构在所有加工过程中均能幸存。取向的无定形成分在热和张力下有助于加工的s / fc纱线具有更高的刚度(模量)和尺寸稳定性.s / fc微观结构的纱线的性能与更常规的热拉伸纱相比。

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