Interdependence Between the Curing,Structure,and the Mechanical Properties of Phenolic Resins

Wolfrum J.; Ehrenstein G.W.

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Interdependence Between the Curing,Structure,and the Mechanical Properties of Phenolic Resins

机译：酚醛树脂的固化，结构与力学性能之间的相互依赖性

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The interdependence between the curing conditions,structure,and the mechanical properties of tow neat phenolic resin systems was investigated.Changes of the distribution of the void diameters were characterized by light-and scanning electron microscope analyses.Tensile tests and dynamic mechanical thermo analysis were performed to determine the influence of the hardener concentration and the curing temperature on the mechanical and the thermomechanical propertis.The study reveals that the hardener concentration predominately influenced the microscopic structure,and thus the mechanical properties of the phenolic resin systems.By varying the postcuring times,it can be shown that independent from the microstructure of the phenolic resin system,the degree of cure has a strong influence on the mechanical properties.

机译：研究了两种纯酚醛树脂体系的固化条件，结构和力学性能之间的相互关系。通过光镜和扫描电镜分析表征了空隙直径分布的变化。进行了拉伸试验和动态力学热分析该研究表明，固化剂浓度主要影响酚醛树脂体系的微观结构，进而影响其力学性能。通过改变后固化时间，可以确定固化剂浓度和固化温度对机械性能和热机械性能的影响。可以看出，固化程度与酚醛树脂体系的微观结构无关，对机械性能有很大影响。

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来源
《Journal of Applied Polymer Science》 |1999年第13期|共13页
作者
Wolfrum J.; Ehrenstein G.W.;
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正文语种 eng
中图分类高分子化学（高聚物）;高分子化合物产品;有机化学;
关键词
phenolic resins; voids; mechanical properties; thermomechanical properties; glass transition temperature;

机译：酚醛树脂;孔隙;机械性能;热机械性能;玻璃化转变温度;

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专利

1. Interdependence Between the Curing,Structure,and the Mechanical Properties of Phenolic Resins [J] . Wolfrum J., Ehrenstein G.W. Journal of Applied Polymer Science . 1999,第13期

机译：酚醛树脂的固化，结构与力学性能之间的相互依赖性
2. Structure-property relationship and influences of phenolic compounds on the mechanical and thermomechanical properties of UV-cured acrylic resin networks [J] . Yin S, Merlin A, Pizzi A, Journal of Applied Polymer Science . 2004,第6期

机译：酚类化合物的结构-性质关系及其对紫外线固化丙烯酸树脂网络机械和热机械性能的影响
3. EFFECT OF NETWORK STRUCTURE ON THERMAL AND MECHANICAL PROPERTIES OF BIPHENOL-TYPE EPOXY RESINS CURED WITH PHENOLS [J] . Ochi M., Sakaga K., Nakanishi Y., Journal of Applied Polymer Science . 1995,第9期

机译：网络结构对苯酚固化的酚型环氧树脂的热力学性能的影响
4. The study of the Novolac type Phenolic Resins: Cure characteristics and Mechanical properties [C] . Tae Ryong Hwang, Sang Min Lee, Yang Sun Song, ANTEC 2004 . 2004

机译：酚醛清漆型酚醛树脂的研究：固化特性和力学性能
5. Using dynamic mechanical analysis to characterize the cure of phenolic resins. [D] . Follensbee, Robert Allen. 1990

机译：使用动态力学分析来表征酚醛树脂的固化。
6. Argon Ion Laser Polymerized Acrylic Resin: A Comparative Analysis of Mechanical Properties of Laser Cured Light Cured and Heat Cured Denture Base Resins [O] . S Srinivasa Murthy, Gargi S Murthy 2015

机译：氩离子激光聚合丙烯酸树脂：激光固化光固化和热固化义齿基料树脂力学性能的比较分析
7. Engineering Plastics-Recent Developments in Synthesis and Applications. Effect of the Chemical Structure of Phenolic Curing Agents on the Network Structure and Mechanical Properties of Cured Epoxy Resins Containing a Mesogenic Group. [O] . Mitsukazu OCHI, Shinji YOSHINAKA, Yoshihiro SHIMIZU 1997

机译：工程塑料 - 最近的合成和应用的发展。酚类固化剂化学结构对含有介晶基团固化环氧树脂网络结构和力学性能的影响。
8. Structure-to-Property Relationships in Addition Cured Polymers 2: Resin TG Composite Initial Mechanical Properties of Norbornenyl Cured Polyimide Resins [R] . Alston, W. B. 1986

机译：加成固化聚合物的结构与性能关系2：降冰片烯固化聚酰亚胺树脂的树脂TG复合物初始力学性能

Interdependence Between the Curing,Structure,and the Mechanical Properties of Phenolic Resins

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