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Diffusion of amine stabilizers in vulcanized natural rubber compositions used in tires

机译:胺稳定剂在轮胎用硫化天然橡胶组合物中的扩散

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摘要

The diffusion of amine stabilizers in vulcanized natural rubber formulations used in tires was investigated. Experiments were undertaken using a "sandwich" system composed of a sample disk containing the additive (source disk) between two external disks of nonadditivated rubber (reception disks). Diffusion coefficients (D) were calculated from the experimental migration curves following the Boltzman-Matano model. Theoretical diffusion curves for the additives were obtained according to the limited extension source in an infinite medium. Experimental data showed reasonable fitting with the theoretical curves, suggesting that D does not depend on the additive concentration. Thermooxidative stability data for the vulcanized rubber containing the additives showed no correlation to the diffusion process. (C) 2000 John Wiley & Sons, Inc. [References: 22]
机译:研究了胺稳定剂在轮胎用硫化天然橡胶配方中的扩散。使用“三明治”系统进行实验,该“三明治”系统由在未添加橡胶的两个外盘(接收盘)之间包含添加剂的样品盘(源盘)组成。根据Boltzman-Matano模型,根据实验迁移曲线计算扩散系数(D)。根据在无限大介质中的有限延伸源,获得了添加剂的理论扩散曲线。实验数据表明与理论曲线合理吻合,表明D不取决于添加剂的浓度。含有添加剂的硫化橡胶的热氧化稳定性数据显示与扩散过程无相关性。 (C)2000 John Wiley&Sons,Inc. [参考:22]

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