Crystal field splitting of lanthanide 4f~(n-1)5d-levels in inorganic compounds

P. Dorenbos

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Crystal field splitting of lanthanide 4f~(n-1)5d-levels in inorganic compounds

机译：无机化合物中镧系4f〜（n-1）5d能级的晶体分裂

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Crystal field splitting of the 4f~(n-1)5d-levels of Ce~(3+) and Eu~(2+) in inorganic compounds is reviewed. A clear correlation between the splitting and the type of anion coordination polyhedron (octahedral, cubal, dodecahedral, tricapped trigonal prism, and cuboctahedral) around the lanthanide ion will be demonstrated. Irrespective of the type of polyhedron, data reveal and R~(-2) dependence of the magnitude of the splitting on the average distance R to the ligands.

机译：综述了无机化合物中Ce〜（3+）和Eu〜（2+）的4f〜（n-1）5d能级的晶格分裂。将证明镧系元素离子周围的阴离子配位多面体的分裂与类型（八面体，古巴，十二面体，三棱三角和立方八面体）之间存在明显的相关性。不管多面体的类型如何，数据揭示了裂隙的大小以及R〜（-2）对配体平均距离R的依赖性。

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《Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics》 |2002年第2期|共4页
作者
P. Dorenbos;
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正文语种 eng
中图分类合金学与各种性质合金;金属材料;
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Phosphors; Crystal and ligand fields; Luminescence;

机译：荧光粉;晶体和配体场;发光;

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1. Crystal field splitting of lanthanide 4f~(n-1)5d-levels in inorganic compounds [J] . P. Dorenbos Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2002,第1a2期

机译：无机化合物中镧系4f〜（n-1）5d能级的晶体分裂
2. Crystal field splitting of highly excited electronic states of the 4f~(n-1) 5d electronic configuration of trivalent rare earth ions in wide band gap crystals [J] . A.C. Cefalas, S. Kobe, Z. Kollia, Crystal engineering . 2002,第3a4期

机译：宽带隙晶体中三价稀土离子的4f〜（n-1）5d电子构型的高激发电子态的晶体场分裂
3. Trends in parameters for the 4f~N reversible 4f~(N-1) 5d spectra of lanthanide ions in crystals [J] . M.F. Reid, L. van Pieterson, A. Meijerink Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2002,第1a2期

机译：晶体中镧系离子的4f〜N可逆4f〜（N-1）5d光谱参数趋势
4. The 5d4f~(n-1) -> 4f~n Luminescence of Trivalent Rare Earth Ions in Inorganic Crystals [C] . P.Dorenbos International Conference on Rare Earths . 1999

机译：在无机晶体中三价稀土离子的5d4f〜（n-1） - > 4f〜n发光
5. LOW-FIELD EPR STUDIES OF OPTICALLY EXCITED AROMATIC TRIPLETS ORIENTED IN SINGLE-CRYSTAL HOSTS (LEAST-SQUARES, CRYSTAL-FIELD, ZERO-FIELD SPLITTING). [D] . LUNDSTEDT, ALAN PAUL. 1984

机译：在单晶体主机（最小二乘，晶体场，零场分裂）中定向激发的光学三元组的低场EPR研究。
6. The coordination chemistry and magnetism of some 3d–4f and 4f amino-polyalcohol compounds [O] . Joseph W. Sharples, David Collison -1

机译：某些3d–4f和4f氨基多元醇化合物的配位化学和磁性
7. Configuration-averaged 4f orbitals in ab initio calculations of low-lying crystal field levels in lanthanide(III) complexes [O] . Heuvel, Willem Van den, Calvello, Simone, Soncini, Alessandro 2016

机译：从头算计算中的配置平均4f轨道镧系元素（III）配合物中的低位晶场水平
8. Crystal Field Splitting in UO sub 2 : An Intermediate Valence Compounds [R] . Andreeff, A., Frauenheim, T., Hennig, K., 1980

机译：UO sub 2中的晶体场分裂：中间价化合物

Crystal field splitting of lanthanide 4f~(n-1)5d-levels in inorganic compounds

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