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Characterization of Ti-Zr-Mn-V-based Laves phase alloys for MH refrigeration system

机译:用于MH制冷系统的Ti-Zr-Mn-V基Laves相合金的表征

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摘要

Ti-Zr-Mn-V based C14 Laves phase alloys have been developed, aiming for application to the metal hydride (MH) refrigeration system, because of their large hydrogen storage capacities and good plateau properties. The melt-spinning process, which was applied to the manufacturing of some of these alloys, could make the plateau slopes much flatter. In the present work, observations of the microstructures were carried out with regard to both Ti-Zr-Mn-V-Fe and Ti-Mn-V-Fe alloys, which are practical compounds for use in the MH refrigeration system. It was revealed that the segregation of zirconium in the Ti_(23)Zr_(10)Mn_(46.5)V_(17)Fe_(3.5) alloy and the precipitation of E9_3 structure oxide phase in the Ti_(35)Mn_(47)V_(15)Fe_3 alloy affected their plateau properties. It appears that, in order to improve the plateau property of these alloys, compositional homogenization and lowering of the oxygen are desirable.
机译:已经开发了基于Ti-Zr-Mn-V的C14 Laves相合金,由于其储氢量大且具有良好的平稳性,旨在应用于金属氢化物(MH)制冷系统。熔融纺丝工艺(用于某些此类合金的制造)可以使平台坡度更加平坦。在目前的工作中,对作为MH制冷系统中实用化合物的Ti-Zr-Mn-V-Fe和Ti-Mn-V-Fe合金进行了显微组织观察。结果表明,Ti_(23)Zr_(10)Mn_(46.5)V_(17)Fe_(3.5)合金中锆的偏析和Ti_(35)Mn_(47)V_中E9_3结构氧化物相的析出(15)Fe_3合金影响了其平台性能。看来,为了改善这些合金的平台性质,组成均质化和降低氧是理想的。

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