Thermodynamic reassessment of the Au-Te system

Jianhua Wang; Xiao-gang Lu; Bo Sundman

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Thermodynamic reassessment of the Au-Te system

机译：Au-Te系统的热力学重新评估

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The Au-Te binary system has been thermodynamically reassessed using the CALPHALD method. The excess Gibbs energy of the liquid phase was formulated with the Redlich-Kister expression and the AuTe_2 intermetallic phase was treated as a stoichiometric compound. A set of self-consistent thermodynamic parameters for each phase has been obtained. Good agreement is reached between the calculated and experimental results. Additionally, the standard formation enthalpy and enthalpy of fusion of AuTe_2 intermetallic phase have also been calculated.

机译：Au-Te二元体系已使用CALPHALD方法进行了热力学重新评估。用Redlich-Kister表达式配制液相的多余吉布斯能量，并将AuTe_2金属间相作为化学计量的化合物处理。已获得每个相的一组自洽热力学参数。在计算结果和实验结果之间达成了良好的一致性。另外，还计算了标准形成焓和AuTe_2金属间相的熔融焓。

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《Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics》 |2006年第2期|共6页
作者
Jianhua Wang; Xiao-gang Lu; Bo Sundman;
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原文格式 PDF
正文语种 eng
中图分类合金学与各种性质合金;
关键词
Thermodynamic properties; Au-Te system; Phase diagram; CALPHAD;

机译：热力学性质Au-Te体系相图CALPHAD;

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Thermodynamic reassessment of the Au-Te system

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