Magneto-optical properties of neodymium-doped LiYF4

H.D.Leebeeck; K.Binnemans

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Magneto-optical properties of neodymium-doped LiYF4

机译：掺钕LiYF4的磁光特性

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In this paper we demonstrate the validity of a semi-empirical approach to describe the magneto-optical properties oflanthanide complexes. The polarised absorption (IR-VIS-UV),magnetic circular dichroism (MCD) and magnetic susceptibilitiesof a LiYF4:Nd3+ (1.5%) single crystal were recorded andanalysed in a temperature region of 4.2 K up to roomtemperature. The crystal structure is obtained by means of X-rayanalysis. Starting values of the free ion, crystal field and intensityparameter sets were obtained by using an additive crystal-fieldmodel based on the coordinates of the eight F- ions in the firstcoordination sphere (S4 symmetry). After several iterations theparameter values are optimised and checked by simulations of theoptical and magneto-optical spectra and by the simulation of themagnetic susceptibilities.

机译：在本文中，我们证明了用半经验方法描述镧系元素络合物的磁光特性的有效性。记录并分析了LiYF4：Nd3 +（1.5％）单晶的极化吸收（IR-VIS-UV），磁圆二色性（MCD）和磁化率，并在高达4.2 K的温度范围内进行了分析。晶体结构通过X射线分析获得。自由离子，晶体场和强度参数组的初始值是通过使用加成晶体场模型获得的，该模型基于第一配位球中八个F-离子的坐标（S4对称性）。经过多次迭代，通过光学和磁光光谱的模拟以及磁化率的模拟来优化和检查参数值。

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《Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics》 |1999年第2期|共12页
作者
H.D.Leebeeck; K.Binnemans;
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正文语种 eng
中图分类合金学与各种性质合金;金属材料;
关键词
Crystal and ligand fields; Optical properties; Light absorption and reflection; Magnetic measurements; Electronic states (localized); 化合物; 磁性; 光学性质; 钕; 锂; 钇; 氟;

机译：Crystal and ligand fields;Optical properties;Light absorption and reflection;Magnetic measurements;Electronic states (localized);化合物;磁性;光学性质;钕;锂;钇;氟;

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1. Magneto-optical properties of neodymium-doped LiYF4 [J] . H.D.Leebeeck, K.Binnemans Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 1999,第1a2期

机译：掺钕LiYF4的磁光特性
2. High-resolution magneto-optical spectroscopy of (LiYF4)-Li-7:Er-167(3+), Er-166(3+) and analysis of hyperfine structure of ultranarrow optical transitions [J] . Gerasimov K. I., Minnegaliev M. M., Malkin B. Z., Physical review, B . 2016,第5期

机译：（LiYF4）-Li-7：Er-167（3 +），Er-166（3+）的高分辨率磁光光谱和超精细结构的超窄光学跃迁分析
3. Magneto-optical performances of novel neodymium-doped CeF_3 crystal [J] . Zhao Geng, Zhao Chengchun, Yang Yilun, Materials Letters . 2021,第Octa1期

机译：新型钕掺杂CEF_3晶体的磁光性能
4. Thermo-Optic Properties of Laser Crystals in the 100-300 K Temperature Range: Y_3Al_5O_(12)(YAG), YAlO3 (YALO), and LiYF4 (YLF) [C] . R. L. Aggarwal, D. J. Ripin, J. R. Ochoa, Society of Photo-Optical Instrumentation Engineers (SPIE);SPIE Proceedings . 2005

机译：激光晶体在100-300 K温度范围内的热光特性：Y_3Al_5O_（12）（YAG），YAlO3（YALO）和LiYF4（YLF）
5. Optical properties and electronic relaxation dynamics of monolayer-protected metal clusters studied using ultrafast pump-probe and magneto-optical spectroscopies [D] . Green, Thomas D. 2016

机译：使用超薄泵探针和磁光光谱研究单层保护金属簇的光学性质和电子弛豫动态
6. Effect of Phase Transformations of a Metal Component on the Magneto-Optical Properties of Thin-Films Nanocomposites (CoFeZr)x (MgF2)100−x [O] . Elena Alexandrovna Ganshina, Vladimir Valentinovich Garshin, Ilya Mikhailovich Pripechenkov, 2021

机译：金属部件相变对薄膜纳米复合材料（COFEZR）X（MGF2）100-X的磁光性质的影响
7. Magneto-optical properties of neodymium-doped LiYF4 [O] . De Leebeeck Hilde, Binnemans Koen, Görller-Walrand Christiane 1999

机译：掺钕LiYF4的磁光特性
8. Determination of the Optical Properties of Neodymium-Doped Glasses [R] . Haugen, G. R. 1966

机译：钕掺杂玻璃光学性质的测定

Magneto-optical properties of neodymium-doped LiYF4

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