Surface and size effects and energy transfer phenomenon on the luminescence of nanocrystalline X_1- Y_2SiO_5:Eu~ (3+)

C.Duan; M.Yin

首页> 外文期刊>Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics >Surface and size effects and energy transfer phenomenon on the luminescence of nanocrystalline X_1- Y_2SiO_5:Eu~ (3+)

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Surface and size effects and energy transfer phenomenon on the luminescence of nanocrystalline X_1- Y_2SiO_5:Eu~ (3+)

机译：纳米晶X_1- Y_2SiO_5：Eu〜（3+）的表面尺寸效应和能量转移现象

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Optical luminescence of nanocrystalline Y_(2-x)Eu_xSiO_5 arises from four distinct sites. We show that onepreviously uncharacterized sites is a Eu~(3+) ion near thesurface of the nanocrystal. The energy transfer rate between thetwo main sites varies with temperature and Eu~(3+)concentration and the dynamics of this transfer is explainedtheoretically. Luminescent quenching occurs at a much higherconcentration and stronger luminescent intensity than in bulkY_2SiO_5:Eu~(3+). This is due to the hindering effects ofparticle boundaries to energy transfer.

机译：纳米晶体Y_（2-x）Eu_xSiO_5的光学发光来自四个不同的位置。我们表明一个以前未表征的位点是纳米晶体表面附近的Eu〜（3+）离子。两个主要位点之间的能量转移速率随温度和Eu〜（3+）浓度而变化，并从理论上解释了这种转移的动力学。与本体Y_2SiO_5：Eu〜（3+）相比，发光猝灭发生在更高的浓度和更强的发光强度上。这是由于粒子边界对能量转移的阻碍作用。

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《Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics》 |2000年第0期|共5页
作者
C.Duan; M.Yin;
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正文语种 eng
中图分类合金学与各种性质合金;金属材料;
关键词
luminescence; nanocrystal; energy transfer;

机译：发光;纳米晶体;能量转移;

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1. Surface and size effects and energy transfer phenomenon on the luminescence of nanocrystalline X_1- Y_2SiO_5:Eu~ (3+) [J] . C.Duan, M.Yin Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2000,第0期

机译：纳米晶X_1- Y_2SiO_5：Eu〜（3+）的表面尺寸效应和能量转移现象
2. High luminescence quantum efficiency of Eu~(3+)-doped SnO_2-SiO_2 glasses due to excitation energy transfer from nano-sized SnO_2 crystals [J] . Tomokatsu Hayakawa, Masayuki Nogami Science and Technology of Advanced Materials . 2005,第1期

机译：纳米SnO_2晶体激发能量转移掺杂Eu〜（3+）的SnO_2-SiO_2玻璃的高发光量子效率。
3. (Eu~(3+)-Nb~(5+))-codoped TiO_2 nanopowders synthesized via Ar/O_2 radio frequency thermal plasma oxidation processing: Phase composition and photoluminescence properties through energy transfer [J] . C.-N. Zhang, J.-G. Li, Y.-H. Leng, Thin Solid Films . 2010,第13期

机译：Ar / O_2射频热等离子体氧化合成（Eu〜（3 +）-Nb〜（5+））共掺杂的TiO_2纳米粉体：通过能量转移的相组成和光致发光性质
4. Observation of energy transfer phenomenon via up and down conversion in Eu~(3+) ions for BaMoO_4:Er~(3+)-Eu~(3+) nanophosphor [C] . Abhishek Kumar Soni, Raghumani Singh Ningthoujam DAE Solid State Physics Symposium . 2018

机译：通过在Eu〜（3 +）离子中的欧杜〜（3 +）离子转化的能量转化现象观察：ER〜（3 +） - EU〜（3）纳米磷
5. Energy transfer and waveguide studies of europium(3+) and terbium(3+)-doped 2 silicon dioxide-titanium dioxide glass prepared via the sol-gel route. [D] . Mancuso, Carmela. 2002

机译：通过溶胶-凝胶法制备的掺（（3+）和ter（3+）的2二氧化硅-二氧化钛玻璃的能量传输和波导研究。
6. Luminescence energy transfer using a terbium chelate: improvements on fluorescence energy transfer. [O] . P R Selvin, J E Hearst 1994

机译：使用a螯合物进行发光能量转移：改善荧光能量转移。
7. Study on the effects of 5d energy locations of Ce^3+ ions on NIR quantum cutting process in Y_2SiO_5: Ce^3+, Yb^3+ [O] . Wenli Zhou, Jie Yang, Jing Wang, 2012

机译：Ce ^ 3 +离子5D能量位置对Y_2SIO_5：Ce ^ 3 +，YB ^ 3 +的5D能量位置对NIR量子切割过程的影响
8. Laser Time-Resolved Spectroscopy: Investigations of Energy Transfer in Eu(3+) and Er(3+) Doped YVO4. [R] . Venikouas, G. E., Powell, R. C. 1977

机译：激光时间分辨光谱：Eu（3+）和Er（3+）掺杂YVO4中能量转移的研究。

Surface and size effects and energy transfer phenomenon on the luminescence of nanocrystalline X_1- Y_2SiO_5:Eu~ (3+)

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