Metalloproteins: structure and function-Geometry and electronic structures of axial/rhombic site in pseudoazurin Met16 variants: XAS and DFT investigations

Takahide Yamaguchi; Junko Yano; Vittal K. Yachandra; Robert K. Szilagyi; Takamitsu Kohzuma

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Metalloproteins: structure and function-Geometry and electronic structures of axial/rhombic site in pseudoazurin Met16 variants: XAS and DFT investigations

机译：金属蛋白：假天青素Met16变体的轴向/斜向位点的几何结构和电子结构：XAS和DFT研究

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Pseudoazurin (PAz) functions as an electron donor to nitrite reductase utilizing Type 1 copper site [1]. The spectroscopic and electrochemical properties of PAz are significantly affected by the mutation of Met16 located at the second coordination sphere of Type 1 copper site [2]. The EPR spectra demonstrated the population of "axial" and "rhombic" site are influenced by the interaction with mutated amino acid at Met16 position [3].

机译：伪天青素（PAz）利用1型铜位点作为亚硝酸还原酶的电子供体[1]。位于1型铜位点第二个配位区域的Met16突变显着影响PAz的光谱和电化学性质[2]。 EPR光谱表明，“轴向”和“菱形”位点的种群受Met16位置突变氨基酸相互作用的影响[3]。

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《Journal of biological inorganic chemistry: JBIC: a publication of the Society of Biological Inorganic Chemistry》 |2014年第null期|共1页
作者
Takahide Yamaguchi; Junko Yano; Vittal K. Yachandra; Robert K. Szilagyi; Takamitsu Kohzuma;
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正文语种 eng
中图分类生物化学;
关键词
demonstrated; significantly; sphere;

机译：证明的;显着的;领域;

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1. 共轭梯度法研究超晶格GaAs/AlxGa1－xAs的电子结构 [J] . 金英进, 姜恩永, 金光日, 天津大学学报（英文版） . 2001,第002期
2. Metalloproteins: structure and function-Geometry and electronic structures of axial/rhombic site in pseudoazurin Met16 variants: XAS and DFT investigations [J] . Takahide Yamaguchi, Junko Yano, Vittal K. Yachandra, Journal of biological inorganic chemistry: JBIC: a publication of the Society of Biological Inorganic Chemistry . 2014,第Null期

机译：金属蛋白：假天青素Met16变体的轴向/斜向位点的几何结构和电子结构：XAS和DFT研究
3. X-ray crystallographic evidence for the simultaneous presence of axial and rhombic sites in cupredoxins: atomic resolution X-ray crystal structure analysis of pseudoazurin and DFT modelling [J] . Yamaguchi T., Akao K., Takashina A., RSC Advances . 2016,第91期

机译：X射线结晶证据，用于同时存在Xial氧毒素中的轴向和菱形位点：原子分辨率X射线晶体结构分析和DFT建模
4. X-ray crystallographic evidence for the simultaneous presence of axial and rhombic sites in cupredoxins: atomic resolution X-ray crystal structure analysis of pseudoazurin and DFT modelling [J] . T. Yamaguchi, K. Akao, A. Takashina, RSC Advances . 2016,第91期

机译：X射线结晶证据，用于同时存在Xial氧毒素中的轴向和菱形位点：原子分辨率X射线晶体结构分析和DFT建模
5. Electronic structures of SrMn_(1-x)Mo_xO_3 (0 < = x < = 0.75) perovskite oxides investigated by XAS and PES [C] . J. H. Hwang, D. H. Kim, S. M. Lee Annual Conference on Magnetism Magnetic Materials . 2011

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机译：硫磺酸XAS和DFT计算丁腈酶：非血红素活性部位的几何和电子结构

Metalloproteins: structure and function-Geometry and electronic structures of axial/rhombic site in pseudoazurin Met16 variants: XAS and DFT investigations

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