Bioorganometallic chemistry-New rhenium complexes for carbon monoxide photorelease

Elham Kianfar; Günther Kn?r

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Bioorganometallic chemistry-New rhenium complexes for carbon monoxide photorelease

机译：生物金属化学-用于一氧化碳光释放的新型rh配合物

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Carbon monoxide has come a long way from just being considered as a silent killer and an environmental pollutant to an important molecular messenger involved in several physiological processes. Recently, important progress has been made towards developing photoactive COreleasing moieties (PhotoCORMs) for possible therapeutic applications [1]. Here, the synthesis and characterization of new rhenium tricarbonyl diimine complexes of the type fac-Re(1,2-diimine)(CO)_3Cl, carrying bis-(phenylimino)acenaphtene ligands (BIAN) 1–3 is reported [2].

机译：一氧化碳从被认为是一种沉默的杀手和一种环境污染物，到参与多个生理过程的重要分子信使，已经走了很长一段路。最近，在开发可能用于治疗应用的光活性相关基团（PhotoCORMs）方面取得了重要进展[1]。在这里，报道了带有双（苯基亚氨基）ac配体（BIAN）1-3的新型fac-Re（1,2-二亚胺）（CO）_3Cl型tri三羰基二亚胺络合物的合成和表征[2]。

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《Journal of biological inorganic chemistry: JBIC: a publication of the Society of Biological Inorganic Chemistry》 |2014年第null期|共1页
作者
Elham Kianfar; Günther Kn?r;
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正文语种 eng
中图分类生物化学;
关键词
messenger; moieties; synthesis;

机译：信使;部分;合成;

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1. Bioorganometallic chemistry-New rhenium complexes for carbon monoxide photorelease [J] . Elham Kianfar, Günther Kn?r Journal of biological inorganic chemistry: JBIC: a publication of the Society of Biological Inorganic Chemistry . 2014,第Null期

机译：生物金属化学-用于一氧化碳光释放的新型rh配合物
2. Towards Cardiolite-Inspired Carbon Monoxide Releasing Molecules - Reactivity of d(4), d(5) Rhenium and d(6) Manganese Carbonyl Complexes with Isocyanide Ligands [J] . Kottelat Emmanuel, Chabert Valentin, Crochet Aurelien, European journal of inorganic chemistry . 2015,第34期

机译：朝向心铁矿启发的一氧化碳释放分子-d（4），d（5）and和d（6）锰羰基配合物与异氰化物配体的反应性
3. Rhenium(I) Carbonyl Complexes of 2,4,6-Tris(2-pyridyl)-1,3,5-triazine(TPT).Rhenium(I)-Promoted Methoxylation of the Triazine Ring Carbon Atom in Dinuclear Rhenium Complexes [J] . Xiaoyuan Chen, Frank J.Femia, John W.Babich, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2001,第12期

机译：2,4,6-三（2-吡啶基）-1,3,5-三嗪（TPT）的Carbon（I）羰基配合物.R（I）促进双核Di络合物中三嗪环碳原子的甲氧基化。
4. SELECTIVE REDUCTION OF CARBON DIOXIDE TO CARBON MONOXIDE WITH RHENIUM(I) COMPLEX (5,5'-BISPHENYLETHYNYL-,2'- BIPYRIDYL)RE(CO)3CL [C] . Engelbert Portenkirchner, Kerstin Oppelt, Christoph Ulbricht American Chemical Society National Meeting . 2012

机译：用铼（I）复合物（5,5'-双苯基乙炔基 - ，2'-双吡啶基）Re（CO）3 Cl，选择性将二氧化碳减少到一氧化碳中
5. I. Symmetrical ligand bridged bimetallic complexes of rhenium(I): Implications for electrocatalytic reduction of carbon dioxide. II. Unimolecular excited state relaxation pathways in polypyridyl complexes of rhenium(I). [D] . Baiano, John Augustus. 1992

机译：I. ligand的对称配体桥联双金属络合物（I）：对电催化还原二氧化碳的影响。二。 poly（I）聚吡啶配合物中的单分子激发态弛豫途径。
6. Rhenium(I) Carbonyl Complexes of 246-Tris(2-pyridyl)-135-triazine (TPT). Rhenium(I)-Promoted Methoxylation of the Triazine Ring Carbon Atom in Dinuclear Rhenium Complexes [O] . Xiaoyuan Chen, Frank J. Femia, John W. Babich, -1

机译：246-三（2-吡啶基）-135-三嗪（TPT）的Carbon（I）羰基配合物。 nu（I）促进双核R配合物中三嗪环碳原子的甲氧基化
7. Structure of carbonyl isocyanide complexes with rhenium and manganese: carbon monoxide releasing molecules for biological applications [O] . Emmanuel Kottelat, Aurélien Crochet, Fabio Zobi 2015

机译：用铼和锰的羰基异氰化物配合物的结构：一氧化碳释放生物应用分子
8. Structure of Adsorbed Sulfur and Carbon on Molybdenum and Rhenium Single Crystal Surfaces, and Their Influence on Carbon Monoxide and Hydrocarbon Chemisorption [R] . Kelly, D. G. 1987

机译：钼和铼单晶表面吸附硫和碳的结构及其对一氧化碳和烃类化学吸附的影响

Bioorganometallic chemistry-New rhenium complexes for carbon monoxide photorelease

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