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首页> 外文期刊>Journal of Chemical and Engineering Data: the ACS Journal for Data >Vapor-Liquid Equilibrium of CO2 in Aqueous Blends of (N-Ethyl-ethanolamine + N-Methyl-diethanolamine) and (N-Ethyl-ethanolamine + 2-Amino-2-methyl-1-propanol)
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Vapor-Liquid Equilibrium of CO2 in Aqueous Blends of (N-Ethyl-ethanolamine + N-Methyl-diethanolamine) and (N-Ethyl-ethanolamine + 2-Amino-2-methyl-1-propanol)

机译:(N-乙基-乙醇胺+ N-甲基-二乙醇胺)和(N-乙基-乙醇胺+ 2-氨基-2-甲基-1-丙醇)的水共混物中的CO2汽-液平衡

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摘要

This work presents experimental vapor—liquid equilibrium data of CO2 over aqueous blends of N-ethyl-ethanolamine (EAE) + N-methyl-diethanol-amine (MDEA) and N-ethyl-ethanolamine (EAE) + 2-amino-2-methyl-1-propanol (AMP) at temperatures of (303.1, 313.1, and 323.1) K and CO2 pressure varying from (0.3 to 550) kPa. Different concentrations of (EAE + MDEA) blends, namely, 0.06/0.24, 0.12/0.18, 0.18/0.12, and 0.24/0.06 mass fraction (mole fraction ratio = 0.0163/0.0487, 0.0328/0.0368, 0.0494/0.0246, 0.0666/0.012S, respectively) were used to determine the vapor-liquid equilibrium of carbon dioxide. Blends of (EAE + AMP) were also studied (mass fraction ratio of 0.06/0.24, 0.12/0.18, 0.15/0.15, 0.24/0.06 or mole fraction ratio = 0.0168/0.0672, 0.0336/0.0504, 0.0420/0.0420, 0.0672/0.0168, respectively) to discover one appropriate composition with a maximum CO2 absorption capability. The aqueous (EAE + MDEA/AMP) blends evolved as better solvents in comparison to aqueous (DEA + MDEA/AMP) and (MAE + MDEA/AMP) with respect to their CO2 absorption capability.
机译:这项工作提出了在N-乙基乙醇胺(EAE)+ N-甲基二乙醇胺(MDEA)和N-乙基乙醇胺(EAE)+ 2-氨基-2-甲基的水性混合物中CO2的气液平衡实验数据(303.1、313.1和323.1)K温度下的1-甲基丙醇(AMP)和CO2压力在(0.3至550)kPa之间变化。不同浓度的(EAE + MDEA)共混物,即0.06 / 0.24、0.12 / 0.18、0.18 / 0.12和0.24 / 0.06质量分数(摩尔分数比= 0.0163 / 0.0487、0.0328 / 0.0368、0.0494 / 0.0246、0.0666 / 0.012 S分别用于确定二氧化碳的气液平衡。还研究了(EAE + AMP)的共混物(质量分数比0.06 / 0.24、0.12 / 0.18、0.15 / 0.15、0.24 / 0.06或摩尔分数比= 0.0168 / 0.0672、0.0336 / 0.0504、0.0420 / 0.0420、0.0672 / 0.0168 )分别发现一种具有最大CO2吸收能力的合适成分。与水性(DEA + MDEA / AMP)和(MAE + MDEA / AMP)相比,水性(EAE + MDEA / AMP)混合物在吸收二氧化碳方面具有更好的溶剂性。

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