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首页> 外文期刊>Journal of Chemical and Engineering Data: the ACS Journal for Data >The Thermodynamic Hydrate Difference Rule (HDR) Applied to Salts of Carbon-Containing Oxyacid Salts and Their Hydrates: Materials at the Inorganic-Organic Interfacet
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The Thermodynamic Hydrate Difference Rule (HDR) Applied to Salts of Carbon-Containing Oxyacid Salts and Their Hydrates: Materials at the Inorganic-Organic Interfacet

机译：适用于含碳含氧盐及其水合物盐的热力学水合物差异法则（HDR）：无机-有机界面处的材料

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摘要

The thermodynamic hydrate difference rule (HDR) has previously been explored largely within the compass of inorganic solids. In this paper we extend its range by studying its application to carbon-containing oxyacid salts, which may be regarded as borderline hydrate-forming inorganic or organic material. We study in detail standard thermodynamic data as it appears in the National Bureau of Standards (NBS) tabulation for formate, carbonate, acetate, glycolate, and oxalate salt hydrates, finding the HDR to apply equally as well to these materials as it does to salts with solely inorganic parents. We use the resulting constants to predict thermodynamic quantities for some parent salts.
机译：热力学水合物差异法则（HDR）先前已在无机固体的指南针中进行了广泛研究。在本文中，我们通过研究其在含碳含氧酸盐中的应用来扩展其范围，该含碳含氧酸盐可被视为临界水合物形成的无机或有机材料。我们详细研究了国家标准局（NBS）表格中关于甲酸盐，碳酸盐，乙酸盐，乙醇酸盐和草酸盐盐水合物的标准热力学数据，发现HDR与盐一样适用于这些材料和纯无机父母在一起。我们使用所得常数来预测某些母体盐的热力学量。

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