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首页> 外文期刊>Journal of chemical crystallography >The true nature of a complex of 1,10-phenanthroline with the ammonium ion; crystal structure of bis-phenanthrolineprotium perchlorate
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The true nature of a complex of 1,10-phenanthroline with the ammonium ion; crystal structure of bis-phenanthrolineprotium perchlorate

机译:1,10-菲咯啉与铵离子配合物的真实性质;双菲咯啉高氯酸盐的晶体结构

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摘要

Herzog's reported bis-1,10-phenanthrolineammonium perchlorate, [(phen)(2)(NH4)](ClO4) is in fact the known 2:1 adduct of 1,10-phenanthroline (phen) with perchloric acid, [(phen)(2)H](ClO4). Its crystal structure, mode of formation, and properties are described. The compound crystallizes in the triclinic space group with P (1) over bar, a = 7.2510(8), b = 13.120(2), c = 22.083(12) Angstrom, alpha = 77.4550(12), beta = 84.45(2), gamma = 82.204(14)degrees, V = 2026.7(6) Angstrom(3), Z = 4, and D-c = 1.510 g cm(-3). It contains cationic columns of alternating 1,10-phenanthroline and its conjugate acid. [References: 24]
机译:赫尔佐格报道的高氯酸双-1,10-菲咯啉铵,[[(phen)(2)(NH4)](ClO4)实际上是1,10-菲咯啉(phen)与高氯酸的已知2:1加合物,[(phen )(2)H](ClO4)。描述了其晶体结构,形成方式和性能。该化合物在三边形空间群中以bar(a = 7.2510(8),b = 13.120(2),c = 22.083(12)埃,alpha = 77.4550(12),beta = 84.45(2)结晶),伽玛= 82.204(14)度,V = 2026.7(6)埃(3),Z = 4,Dc = 1.510 g cm(-3)。它包含交替的1,10-菲咯啉及其共轭酸的阳离子柱。 [参考:24]

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