Synthesis and characterization of Bis(mu-sulfido)bis[{O,O-dimethyldithiophosphato}oxomolybdenum(V)]. Crystal structure of Mo2O2(Phi-S-2)[S2P(OMe)(2)](2 center dot)C6H6

Awwal L; Bingham AL; Drake JE; Hursthouse MB; Light ME; Kumar R; Ratnani R

首页> 外文期刊>Journal of chemical crystallography >Synthesis and characterization of Bis(mu-sulfido)bis[{O,O-dimethyldithiophosphato}oxomolybdenum(V)]. Crystal structure of Mo2O2(Phi-S-2)[S2P(OMe)(2)](2 center dot)C6H6

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Synthesis and characterization of Bis(mu-sulfido)bis[{O,O-dimethyldithiophosphato}oxomolybdenum(V)]. Crystal structure of Mo2O2(Phi-S-2)[S2P(OMe)(2)](2 center dot)C6H6

机译：双（硫代亚砜基）双[{O，O-二甲基二硫代磷酸基}氧钼（V）]的合成与表征。 Mo2O2（Phi-S-2）[S2P（OMe）（2）]（2中心点）C6H6的晶体结构

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Bis(mu-sulfido)bis[{O,O-dimethyldithiophosphato}oxomolybdenum(V) was prepared by dropwise addition of an ethanolic solution of the ammonium salt of O,O-dimethyldithio-phosphoric acid to a hot aqueous solution of MoCl5. The X-ray structure of Mo2O2(Phi-S-2)[S2P(OMe)(2)](2).C6H6 was determined. Crystal data: Monoclinic, P2(1), a = 6.9788(6), b = 22.616(3), c = 14.633(1) angstrom, beta = 101.193(9)degrees, V = 2265.5(4) angstrom(3), Z = 4. The immediate environment around the two molybdenum atoms is essentially square pyramidal if the Mo-Mo interaction is ignored. The terminal oxygen atoms are in the syn conformation.

机译：通过将O，O-二甲基二硫代磷酸铵盐的乙醇溶液滴加到热的MoCl 5水溶液中来制备双（μ-硫代）双[{O，O-二甲基二硫代磷酸根}}氧钼（V）。测定了Mo2O2（Phi-S-2）[S2P（OMe）（2）]（2）.C6H6的X射线结构。晶体数据：单斜晶系，P2（1）/ n，a = 6.9788（6），b = 22.616（3），c = 14.633（1）埃，beta = 101.193（9）度，V = 2265.5（4）埃（ 3），Z =4。如果忽略了Mo-Mo相互作用，则两个钼原子周围的直接环境基本上是方形金字塔形的。末端氧原子处于顺式构象。

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《Journal of chemical crystallography》 |2006年第2期|共6页
作者
Awwal L; Bingham AL; Drake JE; Hursthouse MB; Light ME; Kumar R; Ratnani R;
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正文语种 eng
中图分类晶体学;
关键词
molybdenum; methyl; dithiophosphate; SPECTROSCOPIC CHARACTERIZATION; OXOMOLYBDENUM(IV) COMPLEXES; MO(V) COMPLEXES; MOLYBDENUM; CHEMISTRY; LIGAND; ELECTROCHEMISTRY; DITHIOCARBONATE; ATOM;

机译：钼;甲基;二硫代磷酸盐;光谱表征;氧钼（IV）络合物;钼（V）络合物;钼;化学;配体;电化学;碳酸二甲酯;原子;

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1. Synthesis and characterization of Bis(mu-sulfido)bis[{O,O-dimethyldithiophosphato}oxomolybdenum(V)]. Crystal structure of Mo2O2(Phi-S-2)[S2P(OMe)(2)](2 center dot)C6H6 [J] . Awwal L, Bingham AL, Drake JE, Journal of chemical crystallography . 2006,第2期

机译：双（硫代亚砜基）双[{O，O-二甲基二硫代磷酸基}氧钼（V）]的合成与表征。 Mo2O2（Phi-S-2）[S2P（OMe）（2）]（2中心点）C6H6的晶体结构
2. SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION, AND STRUCTURAL STUDIES OF BIS(MU-SULFIDO)BIS[(O,O-DIALKYL (ALKYLENE) DITHIOPHOSPHATO)OXOMOLYBDENUM(V)] COMPLEXES - CRYSTAL STRUCTURES OF MO2O2S2[S2P(OET)(2)](2), MO2O2S2[S2P(OET)(2)](2)CENTER-DOT-2NC(5)H(5), [J] . Drake JE., Ratnani R., Mislankar AG. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1996,第9期

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8. Oxy- and Thio- Phosphorus Acid Derivatives of Tin. III. The X-ray Crystal and Molecular Structure of Bis-(O-O' -- Diphenyldithiophosphato) tin (II), Sn(s2P(OC6H5)2)2, a Bicyclic Dimer Held Together by h6-C6H5 to Tin (II) Interacti [R] . Hossain, M. B., Lefferts, J. L., Molloy, K. C., 1979

机译：锡的氧 - 和硫 - 磷酸衍生物。 III。双 - （O-O' - 二苯基二硫代磷酸）锡（II），sn（s2p（OC6H5）2）2，双环二聚体由h6-C6H5与锡（II）相互作用的X射线晶体和分子结构

Synthesis and characterization of Bis(mu-sulfido)bis[{O,O-dimethyldithiophosphato}oxomolybdenum(V)]. Crystal structure of Mo2O2(Phi-S-2)[S2P(OMe)(2)](2 center dot)C6H6

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