The preparation, characterization and X-ray structural analysis of tetrakis[1-methyl-3-(2-propyl)-2(3H)-imidazolethione]zinc(II) tetrafluoroborate and tetrakis[1-methyl-3-(1-butyl)-2(3H)-imidazolethione]zinc(II) tetrafluoroborate

Williams DJ; Concepcion JJ; Koether MC; Arrowood KA; Carmack AL; Hamilton TG; Luck SM; Ndomo M; Teel CR; VanDerveer D

首页> 外文期刊>Journal of chemical crystallography >The preparation, characterization and X-ray structural analysis of tetrakis[1-methyl-3-(2-propyl)-2(3H)-imidazolethione]zinc(II) tetrafluoroborate and tetrakis[1-methyl-3-(1-butyl)-2(3H)-imidazolethione]zinc(II) tetrafluoroborate

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The preparation, characterization and X-ray structural analysis of tetrakis[1-methyl-3-(2-propyl)-2(3H)-imidazolethione]zinc(II) tetrafluoroborate and tetrakis[1-methyl-3-(1-butyl)-2(3H)-imidazolethione]zinc(II) tetrafluoroborate

机译：四[1-甲基-3-（2-丙基）-2（3H）-咪唑硫酮]四氟硼酸锌（II）和四[1-甲基-3-（1-丁基）的制备，表征及X射线结构分析）-2（3H）-咪唑硫酮]四氟硼酸锌（II）

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Two compounds, [Zn(mipit)(4)][BF4](2) (1) and [Zn(mnbit)(4)][BF4](2) (2) have been synthesized and characterized via standard solid and solution state methods including single crystal X-ray crystallography (mipit: 1-methyl-3-(2-propyl)-2(3H)-imidazolethione and mnbit: 1-methyl-3-(1-butyl)-2(3H)-imidazolethione). Compound 1 crystallizes in monoclinic space group P2(1) with a = 11.804(2) angstrom, b = 16.710(3) angstrom, c = 25.763(5) angstrom, beta = 90.14(3) and Z = 4, whereas compound 2 crystallizes in tetragonal space group 14 with a = b = 11.6517(16) A, c = 16.820(3) angstrom, and Z = 2. Both complexes are high melting, colorless water soluble 2:1 electrolyte solids that state have flattened tetrahedral ZnS4 coordination geometry. The isopropyl analog is slightly more distorted than the n-butyl analog, and the degree of distortion is not directly related to the steric bulk of the ligand.

机译：[Zn（mipit）（4）] [BF4]（2）（1）和[Zn（mnbit）（4）] [BF4]（2）（2）这两种化合物已经合成，并通过标准固体和溶液进行表征态方法包括单晶X射线晶体学（mipit：1-甲基-3-（2-丙基）-2（3H）-咪唑硫酮和mnbit：1-甲基-3-（1-丁基）-2（3H）-咪唑硫酮）。化合物1在单斜空间群P2（1）/ n中结晶，a = 11.804（2）埃，b = 16.710（3）埃，c = 25.763（5）埃，beta = 90.14（3）和Z = 4，化合物2在a = b = 11.6517（16）A，c = 16.820（3）埃，Z = 2的四边形空间群14中结晶。两种络合物均为高熔点，无色水溶性2：1电解质固体，其状态已变平四面体ZnS4配位几何。异丙基类似物的扭曲程度比正丁基类似物稍大，扭曲程度与配位体的空间体积没有直接关系。

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来源
《Journal of chemical crystallography》 |2006年第8期|共5页
作者
Williams DJ; Concepcion JJ; Koether MC; Arrowood KA; Carmack AL; Hamilton TG; Luck SM; Ndomo M; Teel CR; VanDerveer D;
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正文语种 eng
中图分类晶体学;
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X-ray crystallography; zinc complex; alkylimidazolethione; homoleptic complex; NITRATE;

机译：X射线晶体学;锌络合物;烷基咪唑硫酮;均一络合物;硝酸盐;

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1. The preparation, characterization and X-ray structural analysis of tetrakis[1-methyl-3-(2-propyl)-2(3H)-imidazolethione]zinc(II) tetrafluoroborate and tetrakis[1-methyl-3-(1-butyl)-2(3H)-imidazolethione]zinc(II) tetrafluoroborate [J] . Williams DJ, Concepcion JJ, Koether MC, Journal of chemical crystallography . 2006,第8期

机译：四[1-甲基-3-（2-丙基）-2（3H）-咪唑硫酮]四氟硼酸锌（II）和四[1-甲基-3-（1-丁基）的制备，表征及X射线结构分析）-2（3H）-咪唑硫酮]四氟硼酸锌（II）
2. The Preparation, Characterization and X-ray Structural Analysis of Tetrakis[1-Methyl-3-(2-Propyl)-2(3H)-Imidazolethione]Cadmium(II) Hexafluorophosphate [J] . Williams DJ, Gulla D, Arrowood KA, Journal of chemical crystallography . 2009,第8期

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3. The Preparation, Characterization and X-ray Structural Analysis of Tetrakis[1-Methyl-3-(2-Propyl)-2(3H)-Imidazolethione]Cadmium(II) Hexafluorophosphate [J] . Daniel J. Williams, Daniel Gulla, Kimberly A. Arrowood, Journal of Chemical Crystallography . 2009,第8期

机译：四[1-甲基-3-（2-丙基）-2（3H）-咪唑硫酮]六氟磷酸镉（II）的制备，表征及X射线结构分析
4. Preparation and characterization of zinc (II) phthalocyanine loaded poly-(D,L latic-co-glycolic) acidnanoparticles for Photodynamic Therapy use [C] . Eduardo Ricci Júnior, Juliana Maldonado Marchetti Annual meeting exposition of the Controlled Release Society . 2005

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7. Preparation and Crystal Structure of Tetrakis(mu-1,8-naphthyridine)dimolybdenum(II) Tetrafluoroborate. [O] . Anders Døssing, Sine Larsen, Alexander van Lelieveld, 1999

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The preparation, characterization and X-ray structural analysis of tetrakis[1-methyl-3-(2-propyl)-2(3H)-imidazolethione]zinc(II) tetrafluoroborate and tetrakis[1-methyl-3-(1-butyl)-2(3H)-imidazolethione]zinc(II) tetrafluoroborate

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