Synthesis and crystal structure of a one-dimensional chain cadmium coordination polymer bridged through 1,2-bis(imidazol-1-yl)ethane

Zhang YP; Wang LY; Wang SW; Li BL; Zhang Y

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Synthesis and crystal structure of a one-dimensional chain cadmium coordination polymer bridged through 1,2-bis(imidazol-1-yl)ethane

机译：1,2-双（咪唑-1-基）乙烷桥联的一维链镉配位聚合物的合成与晶体结构

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The cadmium(II) complex [Cd(phba)(2)(bim)(H2O)(2)](n) (1) (phba = 4-hydroxybenzoate, bim = 1,2-bis(imidazol-1-yl)ethane) has been synthesized and structurally characterized by X-ray diffraction analysis. It crystallizes in the monoclinic space group C2/c, a = 23.820(4) angstrom, b = 9.5331(14) angstrom, c = 11.1086(19) angstrom, beta = 111.519(4)degrees, V = 2346.7(7) angstrom(3), Z = 4. The coordination geometry of Cd(II) atom is distorted octahedral; it is coordinated by two nitrogen atoms from the imidazole rings of two symmetry-related bim molecules, and four oxygen atoms from two symmetry-related phba anions and two water molecules. The Cd(II) atoms are bridged by bim molecules to form a one-dimensional chain.

机译：镉（II）配合物[Cd（phba）（2）（bim）（H2O）（2）]（n）（1）（phba = 4-羟基苯甲酸酯，bim = 1,2-双（咪唑-1-基）乙烷）已经合成并通过X射线衍射分析对其结构进行了表征。它在单斜空间群C2 / c中结晶，a = 23.820（4）埃，b = 9.5331（14）埃，c = 11.1086（19）埃，beta = 111.519（4）度，V = 2346.7（7）埃（3），Z =4。Cd（II）原子的配位几何是八面体形的;它由两个对称相关的bim分子的咪唑环中的两个氮原子和两个对称相关的phba阴离子和两个水分子中的四个氧原子配位。 Cd（II）原子被bim分子桥接形成一维链。

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《Journal of chemical crystallography》 |2008年第2期|共4页
作者
Zhang YP; Wang LY; Wang SW; Li BL; Zhang Y;
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正文语种 eng
中图分类晶体学;
关键词
one-dimensional chain; cadmium(II) complex; bis(imidazole) flexible ligand; hydroxybenzoate; coordination polymer; SUPRAMOLECULAR ISOMERISM; MAGNETIC-PROPERTIES; NETWORK; MOLECULES; CATIONS; LIGAND; CO2+;

机译：一维链;镉（II）配合物;双（咪唑）柔性配体;羟基苯甲酸酯;配位聚合物;超分子异构;磁性能;网络;分子;阳离子;配体;CO2 +;

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1. Synthesis and crystal structure of a one-dimensional chain cadmium coordination polymer bridged through 1,2-bis(imidazol-1-yl)ethane [J] . Zhang YP, Wang LY, Wang SW, Journal of chemical crystallography . 2008,第2期

机译：1,2-双（咪唑-1-基）乙烷桥联的一维链镉配位聚合物的合成与晶体结构
2. Synthesis and crystal structure of an infinite double-stranded chain manganese(II) coordination polymer bridged through 1,2-bis(imidazol-1-yl)ethane ligand [J] . Zhu X, Li BL, He XY, Journal of chemical crystallography . 2005,第6期

机译：通过1,2-双（咪唑-1-基）乙烷配体桥接的无限双链锰（II）配位聚合物的合成和晶体结构
3. Synthesis and crystal structure of an infinite double- stranded chain manganese(II) coordination polymer bridged through 1,2-bis(imidazol-1-yl)ethane ligand [J] . Xia Zhu, Baolong Li, Xueyan He, Journal of Chemical Crystallography . 2005,第6期

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4. Syntheses and Crystal Structures of a Series of Cadmium(Ⅱ) Coordination Polymers withEnd-to-end Dicyanamide Bridges [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

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5. Studies into selective fluorination and the coordination chemistry of alkyl iodides and the ligands meso and racemic 1,2-bis(phenylphosphine-oxide)ethane. [D] . Horvath, Michael John. 1994

机译：研究烷基碘与配体的内消旋和外消旋1,2-双（苯基膦氧化物）乙烷的选择性氟化和配位化学。
6. Crystal structure of a novel one-dimensional zigzag chain-like cobalt(II) coordination polymer constructed from 44′-bipyridine and 2-hydroxybenzoate ligands [O] . Thawanrat Saelim, Kittipong Chainok, Filip Kielar, 2020

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7. Crystal structure of catena-polydiaqua-bis(3-carboxy-5-methoxybenzoato-κO)-(1,2-bis(imidazol-1-yl)ethane-κ2N:N′)cobalt(II), C26H28CoN4O12, Co(C9H6O5)2(H2O)2(C8H10N4) [O] . Min-Le Han 2019

机译：Catena-Poly Diaqua-BIS（3-羧基-5-甲氧基苯甲酰o-κM）晶体结构 - （1,2-双（咪唑-1-基）乙烷-κ2N：N'）钴（II），C26H28CON4O12， CO（C9H6O5）2（H2O）2（C8H10N4）

Synthesis and crystal structure of a one-dimensional chain cadmium coordination polymer bridged through 1,2-bis(imidazol-1-yl)ethane

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