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首页> 外文期刊>Journal of chemical crystallography >Crystal and Molecular Structures of C6H5CH2SOCH2CONHCH2C6H5 and C6H5SOCH2CON((C3H7)-C-i)(2)
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Crystal and Molecular Structures of C6H5CH2SOCH2CONHCH2C6H5 and C6H5SOCH2CON((C3H7)-C-i)(2)

机译:C6H5CH2SOCH2CONHCH2C6H5和C6H5SOCH2CON((C3H7)-C-i)(2)的晶体和分子结构

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摘要

The crystal structures for two of the ligands C6H5CH2SOCH2CONHCH2C6H5 (1) and C6H5SOCH2CON(iC(3)H(7)) 2 (2) have been determined by X-ray diffraction. These compounds crystallize in orthorhombic system with space groups and cell parameters, Pca21(no. 29), a = 8.4600(5) angstrom, b = 5.3534(5) angstrom, c = 32.136(2) angstrom, V = 1455.42(15) angstrom(3) and Pna21(no. 33) a = 17.5563 (11) angstrom, b = 5.7902(4) angstrom, c = 14.2866(9) angstrom, V = 1452.30 (16) angstrom(3), respectively. These molecules are stabilized in solid state by various intra and intermolecular hydrogen bonding interactions to give polymeric structures. The reported IR spectra of these compounds in solid state could be explained on the basis of the observed intermolecular hydrogen bonding interactions.
机译:已经通过X射线衍射确定了两个配体C6H5CH2SOCH2CONHCH2C6H5(1)和C6H5SOCH2CON(iC(3)H(7))2(2)的晶体结构。这些化合物在具有空间组和细胞参数的正交晶系中结晶,Pca21(第29号),a = 8.4600(5)埃,b = 5.3534(5)埃,c = 32.136(2)埃,V = 1455.42(15)埃(3)和Pna21(no.33)a = 17.5563(11)埃,b = 5.7902(4)埃,c = 14.2866(9)埃,V = 1452.30(16)埃。这些分子通过各种内部和分子间的氢键相互作用稳定在固态,从而形成聚合物结构。可以根据观察到的分子间氢键相互作用来解释所报告的这些固态化合物的红外光谱。

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