Synthesis, Crystal Structure of catena-poly [[4,4 '-bipyridine-N,N '-bis[(triphenylphosphine)-copper(I)]-pyridine-2-carbaldehyde azine-N,N ':N '',N '''] bis(tetrafluoroboride)]

Mo J; Zhang SM; Ge WZ; Liu JH

首页> 外文期刊>Journal of chemical crystallography >Synthesis, Crystal Structure of catena-poly [[4,4 '-bipyridine-N,N '-bis[(triphenylphosphine)-copper(I)]-pyridine-2-carbaldehyde azine-N,N ':N '',N '''] bis(tetrafluoroboride)]

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Synthesis, Crystal Structure of catena-poly [[4,4 '-bipyridine-N,N '-bis[(triphenylphosphine)-copper(I)]-pyridine-2-carbaldehyde azine-N,N ':N '',N '''] bis(tetrafluoroboride)]

机译：链状聚[[4,4'-联吡啶-N，N'-双[（三苯基膦）-铜（I）]-吡啶-2-甲醛甲醛-N，N'：N''的合成，晶体结构N''']双（四氟硼化物）]

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The title complex [Cu-2(C10H8N2)(C12H10N4) (C18H15)(2)(BF4)(2)](n) has been synthesized and characterized by single crystal X-ray analysis. The compound crystallizes in the monoclinic space group P2(1)/c with a = 10.450(4) angstrom, b = 14.027(5) angstrom, c = 18.950(6) angstrom, beta = 100.459(5)degrees, V = 2,731.7(16) angstrom(3). In the title complex, the cation forms a linear chain, which is bridged by 4,4'-bipyridine and pyridine-2-carbaldehyde azine. The crystallographic asymmetry unit could be expanded polymeric structure using symmetry code: x, 1 + y, z; 1 - x, -y, 1 - z. The Cu(I) atom is coordinated by one P atom of PPh3 ligand, two N atoms of pyridine-2-carbaldehyde azine ligand and one N atom of 4,4'-bipyridine ligand. There is a crystallographic centre of symmetry at the mid-point of the C-C bond between two pyridine rings of 4,4'-bipyridine.

机译：标题配合物[Cu-2（C10H8N2）（C12H10N4）（C18H15）（2）（BF4）（2）]（n）已合成，并通过单晶X射线分析进行了表征。该化合物在单斜空间群P2（1）/ c中以a = 10.450（4）埃，b = 14.027（5）埃，c = 18.950（6）埃，beta = 100.459（5）度，V = 2,731.7结晶（16）埃（3）。在标题配合物中，阳离子形成直链，由4,4'-联吡啶和吡啶-2-甲醛嗪桥接。结晶学上的不对称单元可以使用对称代码：x，1 + y，z;和/或x; 1，y，z来扩展。 1-x，-y，1-z。 Cu（I）原子由PPh3配体的一个P原子，吡啶-2-甲醛甲醛配体的两个N原子和4,4'-联吡啶配体的一个N原子配位。在4，4′-联吡啶的两个吡啶环之间的C-C键的中点有一个对称的晶体学中心。

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来源
《Journal of chemical crystallography》 |2009年第12期|共4页
作者
Mo J; Zhang SM; Ge WZ; Liu JH;
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正文语种 eng
中图分类晶体学;
关键词
Crystal structure; Cu(I) complex; 4; 4 '-Bipyridine; Pyridine-2-carbaldehyde; Coordination polymer;

机译：晶体结构;Cu（I）配合物;4;4'-联吡啶;吡啶-2-甲醛;配位聚合物;

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1. Synthesis, Crystal Structure of catena-poly [[4,4 '-bipyridine-N,N '-bis[(triphenylphosphine)-copper(I)]-pyridine-2-carbaldehyde azine-N,N ':N '',N '''] bis(tetrafluoroboride)] [J] . Mo J, Zhang SM, Ge WZ, Journal of chemical crystallography . 2009,第12期

机译：链状聚[[4,4'-联吡啶-N，N'-双[（三苯基膦）-铜（I）]-吡啶-2-甲醛甲醛-N，N'：N''的合成，晶体结构N''']双（四氟硼化物）]
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4. Supramolecular structure in the cocrystal of 3, 5-bispyridyl-1-H-1, 2, 4-triazole and 4,4'-oxybis(benzoic acid) [C] . Li Ting, Li Bing, Chen Xiao-Yan International Conference on Chemical Engineering and Advanced Materials . 2013

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Synthesis, Crystal Structure of catena-poly [[4,4 '-bipyridine-N,N '-bis[(triphenylphosphine)-copper(I)]-pyridine-2-carbaldehyde azine-N,N ':N '',N '''] bis(tetrafluoroboride)]

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