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首页> 外文期刊>Journal of chemical crystallography >Synthesis and crystal structure of 4-(tert-butyl)-N-(pyridin-3-ylmethyl) benzenesulfonamide
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Synthesis and crystal structure of 4-(tert-butyl)-N-(pyridin-3-ylmethyl) benzenesulfonamide

机译：4-（叔丁基）-N-（吡啶-3-基甲基）苯磺酰胺的合成及晶体结构

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摘要

Reaction between 4-tert-butylphenyl sulfonyl chloride and 3-picolylamine in presence of triethylamine lead to the formation of 4-(tert-butyl)-N-(pyridin-3- ylmethyl) benzenesulfonamide. This compound crystallized in a triclinic space group, P-1, with cell parameters a = 6.7945 (2), b = 7.1791 (3), c = 17.1267 (7), α = 96.153 (1), β = 100.573 (2), γ = 98.911 (2) and Z = 2, with the whole molecule being the asymmetric unit. The compound has extensive π-π interactions along c-axis between the phenyl ring and the pyridyl ring at a distance of ~3.7 ?. In addition, the crystal also has a nearly linear intermolecular N-H···N hydrogen bond at a relatively short distance of 1.96 ?. Graphical Abstract: The title compound has extensive π-π interactions along c-axis between phenyl ring and the pyridyl ring at a distance of ~3.7 ?. In addition, the crystal also has a nearly linear intermolecular N-H···N hydrogen bond at a relatively short distance of 1.96 ?. Packing diagram of the title compound along c-axis showing π-π stacking.[Figure not available: see fulltext.]
机译：在三乙胺存在下4-叔丁基苯基磺酰氯与3-吡啶甲基胺之间的反应导致形成4-（叔丁基）-N-（吡啶-3-基甲基）苯磺酰胺。该化合物在三斜晶空间群P-1中结晶，单元参数为a = 6.7945（2），b = 7.1791（3），c = 17.1267（7），α= 96.153（1），β= 100.573（2） ，γ= 98.911（2）和Z = 2，整个分子是不对称单元。该化合物沿c轴在苯环和吡啶基环之间的〜3.7距离处具有广泛的π-π相互作用。另外，该晶体在1.96λ的相对短距离处还具有几乎线性的分子间N-H···N氢键。图解摘要：该标题化合物在c轴上于苯环和吡啶环之间的〜3.7距离处具有广泛的π-π相互作用。另外，该晶体在1.96λ的相对短距离处还具有几乎线性的分子间N-H···N氢键。标题化合物沿c轴的堆积图，显示π-π堆积。[图不可用：请参见全文。

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