Synthesis and Structure of [Fe3O(O2CCH2OMe)(6)(H2O)(3)][FeCl4]

Ogrin D; Barron AR

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Synthesis and Structure of [Fe3O(O2CCH2OMe)(6)(H2O)(3)][FeCl4]

机译：[Fe3O（O2CCH2OMe）（6）（H2O）（3）] [FeCl4]的合成与结构

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The structure of [Fe3O(O2CCH2OMe)(6)(H2O)(3)] [FeCl4] center dot 2.5H(2)O has been determined. The three iron atoms and the mu(3)-oxo are coplanar. Each carboxylic ligand is bidentate and links two iron atoms in the cluster. The clusters are linked by intra-trimer hydrogen bonding to form a zigzag motif that forms sheets via hydrogen bonding involving disordered waters of hydration. The [FeCl4](-) anion is intercalated between the hydrogen-bonded sheets. Crystal data: space group P2(1), a = 10.276(2), b = 22.793(5), c = 17.091(3)angstrom, beta = 96.66(3)degrees, V = 3976(1)angstrom(3), Z = 4, R = 0.0837, wR(2) = 0.1836.

机译：确定了[Fe3O（O2CCH2OMe）（6）（H2O）（3）] [FeCl4]中心点2.5H（2）O的结构。三个铁原子和mu（3）-oxo共面。每个羧基配体都是双齿的，并连接簇中的两个铁原子。这些簇通过三聚体内部氢键连接形成一个之字形基序，该基字形通过涉及无序水合水的氢键形成薄片。 [FeCl4]（-）阴离子插在氢键片之间。晶体数据：空间群P2（1）/ n，a = 10.276（2），b = 22.793（5），c = 17.091（3）埃，beta = 96.66（3）度，V = 3976（1）埃（ 3），Z = 4，R = 0.0837，wR（2）= 0.1836。

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《Journal of chemical crystallography》 |2009年第1期|共5页
作者
Ogrin D; Barron AR;
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正文语种 eng
中图分类晶体学;
关键词
Iron; Carboxylate; Oxo; Trimer; Sheet; Zigzag;

机译：铁;羧酸盐;氧代;三聚体;片状;之字形;

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Synthesis and Structure of [Fe3O(O2CCH2OMe)(6)(H2O)(3)][FeCl4]

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