首页> 外文期刊>Journal of chemical crystallography >Synthesis and structure determination of a new layered zincophosphate: [H_2N_2C_6H_(16)]_(0.5)[Zn_2(PO_4)(HPO_4)(H_2O)] centre dot H_2O
【24h】

Synthesis and structure determination of a new layered zincophosphate: [H_2N_2C_6H_(16)]_(0.5)[Zn_2(PO_4)(HPO_4)(H_2O)] centre dot H_2O

机译:新型层状磷酸锌的合成与结构确定:[H_2N_2C_6H_(16)] _(0.5)[Zn_2(PO_4)(HPO_4)(H_2O)]中心点H_2O

获取原文
获取原文并翻译 | 示例
           

摘要

The synthesis and crystal structure of a new microporous zincophosphate are described. [H_2N_2C_6H_(16)]_(0.5)[Zn_2(PO_4)(HPO_4)(H_2O)] centre dot H_2O crystallizes in the triclinic space group P1-bar with a = 8.822(4), b = 9.236(4), c = 8.451(3) A, #alpha# = 67.19(3), #beta# = 91.32(3), #gamma# = 111.10(3) deg, V = 586.7(4) A~3 and Z = 2. This new material consists of infinite two-dimensional anionic layers alternated with planes containing organic diprotonated templates, N, N, N', N'-tetramethylethylenediamine [H_2N_2C_6H_(16)]~(2+) molecules. The framework structure is built up of ZnO_4, ZnO_3OH_2 ,PO_4 and PO_3OH tetrahedra, linked through oxygen vertices. The presence of terminal OH_2 and OH groups, leads to an open structure containing four- and eight-rings. The organic molecules are interconnected to the framework through hydrogen bonds.
机译:描述了新型微孔磷酸锌的合成和晶体结构。 [H_2N_2C_6H_(16)] _(0.5)[Zn_2(PO_4)(HPO_4)(H_2O)]中心点H_2O在三斜晶空间群P1-bar中结晶,其a = 8.822(4),b = 9.236(4),c = 8.451(3)A,#alpha#= 67.19(3),#beta#= 91.32(3),#gamma#= 111.10(3)deg,V = 586.7(4)A〜3,Z =2。这新材料由无限的二维阴离子层与包含有机双质子化模板,N,N,N',N'-四甲基乙二胺[H_2N_2C_6H_(16)]〜(2+)分子的平面交替组成。框架结构由通过氧顶点连接的ZnO_4,ZnO_3OH_2,PO_4和PO_3OH四面体组成。末端OH_2和OH基团的存在导致形成包含四个和八个环的开放结构。有机分子通过氢键与骨架相互连接。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号