On the Coordination Behaviour of the hmta Toward Alkali Metal Cations in Presence of Perchlorate Anions

Kruszynski Rafal; Sieranski Tomasz; Swiatkowski Marcin; Zielak Marta; Wojciechowski Jakub; Dzierzawska Magdalena; Czubacka Ewelina

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On the Coordination Behaviour of the hmta Toward Alkali Metal Cations in Presence of Perchlorate Anions

机译：高氯酸根阴离子存在下hmta对碱金属阳离子的配位行为

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The lithium and sodium perchlorate coordination compounds with hexamethylenetetramine of general formulas: [Li(H2O)(4)](+)aEuro cent 2hmtaaEuro cent ClO4 (-) (1) and [Na(ClO4)(H2O)(hmta)](n) (2) have been synthesized, characterised by elemental and thermal analysis, IR spectroscopy and X-ray crystallography. The compound 2 is a rare three dimensional hybrid compound. The obtained compounds are air stable at room temperature and well soluble in water. As a result of the different electronic properties of the ions, the compounds differ considerably in the molecular structure and consequently in the properties. The studied compounds exhibit opposite placement of both hmta molecules and perchlorate ions: in an outer and inner coordination sphere, respectively, for 1 and 2. The thermal and spectroscopic properties were correlated with the studied compounds molecular structure.

机译：高氯酸锂和高氯酸锂与六亚甲基四胺的配位化合物，其通式为：[Li（H2O）（4）]（+）a欧分2hmtaa欧分ClO4（-）（1）和[Na（ClO4）（H2O）（hmta）]（ n）（2）已合成，其特征在于元素分析和热分析，红外光谱和X射线晶体学。化合物2是稀有的三维杂化化合物。所获得的化合物在室温下是空气稳定的并且很好地溶于水。由于离子具有不同的电子特性，因此这些化合物的分子结构也不同，因此其特性也不同。所研究的化合物在hmta分子和高氯酸根离子上的位置相反：分别在外部和内部配位球中1和2。热学和光谱学性质与所研究化合物的分子结构相关。

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《Journal of chemical crystallography》 |2015年第12期|共11页
作者
Kruszynski Rafal; Sieranski Tomasz; Swiatkowski Marcin; Zielak Marta; Wojciechowski Jakub; Dzierzawska Magdalena; Czubacka Ewelina;
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正文语种 eng
中图分类晶体学;
关键词
Lithium; Sodium; Perchlorate; Hexamethylenetetramine; Thermal decomposition; IR spectroscopy;

机译：锂;钠;高氯酸盐;六亚甲基四胺;热分解;红外光谱;

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1. On the Coordination Behaviour of the hmta Toward Alkali Metal Cations in Presence of Perchlorate Anions [J] . Kruszynski Rafal, Sieranski Tomasz, Swiatkowski Marcin, Journal of chemical crystallography . 2015,第10a12期

机译：高氯酸根阴离子存在下hmta对碱金属阳离子的配位行为
2. Coordination and supramolecular assemblies of mono-hydroxylated octamethylcucurbit[6] uril with alkali and alkaline earth metal ions in the presence of polychloride cadmium anions [J] . Shen Fang-Fang, Zhao Jiang-Lin, Chen Kai, CrystEngComm . 2017,第28期

机译：用碱金属和碱土金属离子在聚氯化物镉阴离子存在下与碱和碱土金属离子的配位和超分子组装
3. Coordination of alkali and alkaline-earth metal ions to perhydroxycucurbit[5]uril and formation of supramolecular self-assemblies in the presence of [SiW12O40](4-) anions [J] . Chen Hai-Yong, Hou Hai-Ting, Liang Zheng-Yun, Inorganica Chimica Acta . 2016,第Null期

机译：在[SiW12O40]（4-）阴离子存在下，碱金属和碱土金属离子与过羟基葫芦[5]的配位和超分子自组装的形成
4. REDUCED DEACTIVATION OF V2O5/AC CATALYST FOR LOW TEMPERATURE SCR BY ALKALI METALS WHEN USED IN PRESENCE OF LOW SO2 [C] . Xianlong Zhang, Xueping Wu, Zhanggen Huang, The 7th China-Korea Workshop on Clean Energy Technology（第七届中韩清洁能源技术研讨会） . 2008

机译：当存在低SO2时，碱金属降低V2O5 / AC催化剂对低温SCR的失活
5. Tetradipicolyamine-substituted resorc[4]arene cavitands: I. Anion binding and transition metal assembled coordination cages and nanoarchitectures. II. Polymer inclusion membranes applied to anion separations. [D] . Gardner, Joseph S. 2005

机译：Tetradipicolyamine取代的间苯二酚[4]芳烃空洞：I.阴离子结合和过渡金属组装的配位笼和纳米结构。二。适用于阴离子分离的聚合物包合物膜。
6. The Effects of Alkali Metal Cations and Common Anions on the Frog Skin Potential [O] . Barry D. Lindley, T. Hoshiko 1964

机译：碱金属阳离子和常见阴离子对青蛙皮肤电位的影响
7. On the Coordination Behaviour of the hmta Toward Alkali Metal Cations in Presence of Perchlorate Anions [O] . 2015

机译：高氯酸根阴离子存在下hmta对碱金属阳离子的配位行为

On the Coordination Behaviour of the hmta Toward Alkali Metal Cations in Presence of Perchlorate Anions

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