Interaction of N-(4-methoxyphenyl)-2,4,6,-trinitroaniline with tris(triphenylphosphinegold)oxonium tetrafluoroborate; X-ray structure of salt [O(AuPPh3)(3)](2) 2{(4-MeO)C6H4-N-C6H2-[2,4,6-(NO)(2)](3)}

Kuzmina LG; Churakov AV; Grandberg KI; Howard JAK

首页> 外文期刊>Journal of chemical crystallography >Interaction of N-(4-methoxyphenyl)-2,4,6,-trinitroaniline with tris(triphenylphosphinegold)oxonium tetrafluoroborate; X-ray structure of salt [O(AuPPh3)(3)](2) 2{(4-MeO)C6H4-N-C6H2-[2,4,6-(NO)(2)](3)}

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Interaction of N-(4-methoxyphenyl)-2,4,6,-trinitroaniline with tris(triphenylphosphinegold)oxonium tetrafluoroborate; X-ray structure of salt [O(AuPPh3)(3)](2) 2{(4-MeO)C6H4-N-C6H2-[2,4,6-(NO)(2)](3)}

机译：N-（4-甲氧基苯基）-2,4,6，-三硝基苯胺与四氟硼酸三（三苯基膦金）氧鎓的相互作用;盐[O（AuPPh3）（3）]（2）2 {（4-MeO）C6H4-N-C6H2- [2,4,6-（NO）（2）]（3）}的X射线结构

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The structure of the auration product of N-(5-methoxybenzene)-2,4,6-trinitroaniline is determined. The compound of composition C67H54Au3N4O8P3 (3) crystallizes in triclinic space group P (1) over bar with a 13.8280(4), b = 14.7641(4), c = 17.4531(5) angstrom, alpha = 111.550(1), beta = 102.779(1), gamma = 103.040(1)degrees, Z = 2. The compound represents a salt tris(triphenylphosphinegold) oxonium N-(4-methoxyphenyl)-2,4,6-trinitroanilinate, with a hexanuclear dimeric structure of the cation and a para-quinoid form of the anion that is responsible for the dark-red color of the compound.

机译：确定了N-（5-甲氧基苯）-2,4,6-三硝基苯胺的乙酰化产物的结构。组成为C67H54Au3N4O8P3的化合物（3）在三边形空间群P（1）中以13.8280（4），b = 14.7641（4），c = 17.4531（5）埃，α= 111.550（1），β= 102.779（1），γ= 103.040（1）度，Z =2。该化合物表示盐N-（4-甲氧基苯基）-2,4,6-三硝基苯胺盐三（三苯基膦金）氧鎓，具有六核二聚结构阳离子和阴离子的对醌形式，是化合物的暗红色。

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《Journal of chemical crystallography》 |2005年第8期|共6页
作者
Kuzmina LG; Churakov AV; Grandberg KI; Howard JAK;
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正文语种 eng
中图分类晶体学;
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Au(I)-complex; chemical and structural analogy of AuL(+) and HgR(+); color-structure correlation; CHEMISTRY;

机译：Au（I）-络合物;AuL（+）和HgR（+）的化学和结构比喻;颜色-结构相关;化学;

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1. Interaction of N-(4-methoxyphenyl)-2,4,6,-trinitroaniline with tris(triphenylphosphinegold)oxonium tetrafluoroborate; X-ray structure of salt [O(AuPPh3)(3)](2) 2{(4-MeO)C6H4-N-C6H2-[2,4,6-(NO)(2)](3)} [J] . Kuzmina LG, Churakov AV, Grandberg KI, Journal of chemical crystallography . 2005,第8期

机译：N-（4-甲氧基苯基）-2,4,6，-三硝基苯胺与四氟硼酸三（三苯基膦金）氧鎓的相互作用;盐[O（AuPPh3）（3）]（2）2 {（4-MeO）C6H4-N-C6H2- [2,4,6-（NO）（2）]（3）}的X射线结构
2. SYNTHESIS AND CHARACTERIZATION OF STERICALLY HINDERED DIARYLSILANES CONTAINING 2,4,6-TRIMETHYLPHENYL AND 2,4,6-TRIS(TRIFLUOROMETHYL)PHENYL SUBSTITUENTS, X-RAY CRYSTAL STRUCTURE OF BIS[2,4,6-TRIS(TRIFLUOROMETHYLPHENYL)]FLUOROSILANE [J] . Braddockwilking J., Brammer L., Huhmann J., Journal of Organometallic Chemistry . 1995,第1a2期

机译：含2,4,6-三甲基苯基和2,4,6-三（三氟甲基）苯基取代基的位阻二芳基化合物的合成与表征，双[2,4,6-三氟]甲苯的X射线晶体结构
3. MAGNETIC PROPERTIES OF STABLE N-[(DICHLOROPHENYL)THIO]-2,4,6-TRIPHENYLPHENYLAMINYL AND N-[(DICHLOROPHENYL)THIO]-2,4,6-TRIS(CHLOROPHENYL)PHENYLAMINYL RADICAL CRYSTALS [J] . Teki Y., Okada A., Yamakage H., Chemical Physics Letters . 1997,第5a6期

机译：稳定的N-[（二氯苯基）噻吩] -2,4,6-三苯酚亚胺基和N-[[（二氯苯基）噻吩] -2,4,6-三（氯苯酚）苯胺基自由基）的磁性
4. Synthesis and X-ray Structural Study on the Complexes of Silver(I) Halide with Tricyclohexylephosphine, Diphenyl-(2,4,6-trimethoxy)phenylphosphine, Phenyl-2,4,6-trimethoxyphenyl phosphine, and Tris(2,4,6-trimethoxy)phenylphosphine [C] . Effendya, A. H. White International Conference on Neutron and X-Ray Scattering . 2008

机译：用三环己磷，二苯基 - （2,4,4,4,6-三甲氧基）苯基膦，苯基-2,4,6-三甲氧基苯基膦，以及三（2,4，）银（I）卤化物的合成和X射线结构研究6-三甲氧基）苯基膦
5. X-ray Crystal Structures Of: [Rh2(N-{2,4,6-CH 3}C6H2)COCH3)4]˙2NCC 6H4 and Ba1.5[Fe(C10H13N 2O7)][Co(CN)6]˙9H2O; Two Crystallographic Challenges [D] . Kpogo, Kenneth Kwame. 2013

机译：X射线晶体结构：[RH2（N- {2,4,6-CH 3} C6H2）COCH3）4]χ2NCC6H4和BA1.5 [Fe（C10H13N 2O7）] [CO（CN）6]˙ 9H2O;两个晶体挑战
6. The effect of counter ions on the far-infrared spectra of tris(triphenylphosphinegold)oxonium dimer salts [O] . Trystan Bennett, Alexander J. Falcinella, Reuben J. White, 2015

机译：抗衡离子对三（三苯基膦）的氧铵二聚盐远红外光谱的影响
7. Solid State Solution Behavior of Triorganotin (IV) Derivatives Containing the2,4,6-Tris-(Triflu oromethyl)Benzene 1,4-Bis(Perfluoroisopropoxy) Tetrafluorobenzene Ligands: Crystal Molecular Structures of 2,4,6-(CF3)3C6H2Sn(C6H5)3 and 1,4-(CH3)SnOC(CF)32C6F [R] . Vij, A., Kirchmeier, R. L., Willett, R. D., 1994

机译：含有2,4,6-三 - （三氟甲基）苯1,4-双（全氟异丙氧基）四氟苯配体的三有机锡（Ⅳ）衍生物的固态溶液行为：2,4,6-（CF3）3C6H2sn的晶体分子结构（ C 6 H 5）3和1,4-（CH 3）snOC（CF）32C6F

Interaction of N-(4-methoxyphenyl)-2,4,6,-trinitroaniline with tris(triphenylphosphinegold)oxonium tetrafluoroborate; X-ray structure of salt [O(AuPPh3)(3)](2) 2{(4-MeO)C6H4-N-C6H2-[2,4,6-(NO)(2)](3)}

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